离子液体溶解纤维素研究进展
赵寿典1 ,刘 晨2 ,侯茗旺1 ,郭 珂1 ,刘 冉1 ,张 娟1 ,赵地顺1
1.河北科技大学 化学与制药工程学院,河北 石家庄 050018;2.石家庄科技信息职业学院 医学与制药工程学院,河北 石家庄 050000
Research process of dissolution of cellulose in ionic liquid
Zhao Shoudian1 , Liu Chen2 , Hou Mingwang1 , Guo Ke1 , Liu Ran1 , Zhang Juan1 , Zhao Dishun1
1.College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018, China; 2.College of Medicine and Pharmaceutical Engineering,Shijiazhuang Career College of Technology and Information,Shijiazhuang 050000, China
摘要 介绍了离子液体的制备方法,综述了[Bmim]C1、[Bmim]OAc、[Emim]OAc、[Hemim]- Cl、[Amim]Cl等咪唑类离子液体溶解纤维素的研究进展,阐述了温度、压力、溶解时间等条件对离子液体溶解纤维素的影响,讨论了离子液体溶解纤维素的机理和溶解特性,提出了离子液体作为新型溶剂溶解纤维素的研究处于起步阶段,其溶解机理和诸多相关的物理化学问题有待进一步研究;随着功能化离子液体溶解纤维素机理的深入研究,离子液体作为纤维素的绿色溶剂必将为开发新型高品质的纤维素制品带来更加广阔的前景。
关键词 :
纤维素 ,
离子液体 ,
溶解
Abstract :The preparation methods of ionic liquids were introduced, and the research progress of the dissolution of cellulose in ionic liquids such as [Bmim]C1, [Bmim]OAc, [Emim]OAc, [Hemim]Cl, [Amim]Cl was summarized. The effects of temperature and pressure etc. on the dissolution of cellulose in ionic liquid were expounded, and the dissolution mechanism and characteristic were discussed. It is pointed out that the research on ionic liquid as a new solvent to dissolve cellulose is still in its infancy, the dissolving mechanism and the problems about physicochemistry remain to be further studied. With the further study of mechanism of function ionic liquid to dissolve cellulose, ionic liquid as green solvents to dissolve cellulose will bring more broad prospects for the development of new high-quality cellulose products .
Key words :
cellulose
ionic liquid
dissolution
通讯作者:
刘 冉(1983—),男,河北石家庄人,讲师。E-mail:lrddlr@126.com
引用本文:
赵寿典,刘 晨,侯茗旺,郭 珂,刘 冉,张 娟,赵地顺. 离子液体溶解纤维素研究进展[J]. 煤炭与化工, 2016, 39(4): 25-27,35.
Zhao Shoudian, Liu Chen, Hou Mingwang, Guo Ke, Liu Ran, Zhang Juan, Zhao Dishun. Research process of dissolution of cellulose in ionic liquid. CCI, 2016, 39(4): 25-27,35.
链接本文:
http://www.mtyhg.com.cn/CN/10.19286/j.cnki.cci.2016.04.008 或 http://www.mtyhg.com.cn/CN/Y2016/V39/I4/25
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