离子液体作为金属缓蚀剂的研究进展
王 明,刘 静,赵寿典,郭 珂,侯茗旺,刘 冉
河北科技大学 化学与制药工程学院,河北 石家庄 050018
Research Progress of Ionic Liquids as Corrosion Inhibitor
for Metals
WANG Ming,LIU Jing,ZHAO Shou-dian,GUO Ke,HOU Ming-wang,LIU Ran
College of Chemistry and Chemical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018,China
摘要 金属材料由于其良好的特性,广泛应用于各种领域,但是金属在酸性或碱性环境中易被腐蚀,可以采用在介质中添加缓蚀剂的方法来抑制。根据大量国内外有关离子液体在缓蚀方面的研究,综述了近年来有关缓蚀作用的离子液体的研究情况,并对离子液体在缓蚀方面的前景进行了展望。提出需进一步研究功能化离子液体,通过引入新的基团提高其缓蚀性能是当前研究的重点,利用离子液体的缓蚀性能将其应用于锌锰电池中,是离子液体的新应用领域。
关键词 :
离子液体 ,
缓蚀 ,
吸附
Abstract :Because of good properties, metallic materials are widely used in various fields. Because metals in acidic or alkaline environment are susceptible to corrosion, corrosion inhibitors would be added in the medium to inhibit corrosion of metals. The development of ionic liquids as corrosion inhibitors for metals in recent years were reviewed, and the research prospects were also presented. It was pointed out that the functional ionic liquids need to be researched further, the introduction of a new group to improve their corrosion performance is the focus of the current study, the new field of ionic liquids is they are used in the zinc manganese battery based on corrosion inhibitors.
Key words :
ionic liquid
inhibition
adsorption
基金资助: 国家级大学生创新创业训练计划项目资助(项目编号:201410082002)
作者简介 : 王 明(1993—),男,河北保定人,本科在校生。E-mail:1216015142@qq.com
[ 1 ] 何 毅,徐中浩,陈航宇,等. 金属材料防腐技术的研究进展[J]. 应用化工,2013,( 11 ):2 065-2 067,2 071.[ 2 ] 刘 莉. 缓蚀剂在金属防腐技术中的应用[ J ]. 广东化工,2014,( 18 ):123 - 139.[ 3 ] 李汝雄, 王建基. 绿色溶剂—离子液体的制备与应用[J]. 化工进展,2002,( 21 ): 43 - 48.[ 4 ] Wikes J S, Zaworotko M J. A novel metal-organic ternary topology constructed from triangular, square and tetrahedral molecular building blocks [J].Chemical Communications,1992;13:965-967.[ 5 ] 于佳音,于洪峰. 常用离子液体研究进展评述[ J ]. 科技资讯,2010,( 25 ):8.[ 6 ] 王风彦,邵光杰. 离子液体应用研究进展[ J ].化学试剂,2009,( 1 ):25 - 30.[ 7 ] 邓有全. 离子液体—21世纪的绿色材料[J].中国高校科技与产业化,2003,( 11 ):33 - 35.[ 8 ] 宗 鹏. 季铵盐型酸化缓蚀剂的合成及其缓蚀机理研究[D]. 中国石油大学,2008.[ 9 ] 徐效陵,黄宝华,刘 军,等. 盐酸溶液中吡咯烷酮离子液 体对碳钢的缓蚀性能[ J ].中国腐蚀与防护学报,2011,( 5 ):336-340.[10] 冷 菁. 新型离子液体的缓蚀性能研究[D].南京理工大学,2012.[11] Qibo Zhang, Yixin Hua. Corrosion inhibition of aluminum in hydrochloric acid solution by alkyl-imidazole ionic liquids[J].Materials Chemistry and Physics,2010, 119: 57-64 [12] Qbio Zhang, Yixin Hua. Corrosion inhibition of mild steel by alkyl imidazole ionic liquids in hydrochloric acid[J]. Electrochemical Acta, 2009, 54: 1 881-1 887.[13] 苑 敬,徐桂英.咪唑Gemini表面活性剂对碳钢的缓蚀性能[C].//中国化学会.中国化学会第29届学术年会摘要集——第26分会:胶体与界面.中国化学会,2014.[14] I Lozano, E Mazario, C O Olivares-Xometl. Corrosion behaviour of API 5LX52 steel in HCl and H2SO4 media in the presence of 1,3-dibencilimidazolio acetate and 1,3-dibencilimidazolio dodecanoate ionic liquids as inhibitors[J]. Materials Chemistry and physics,2014,147:191-197.[15] E Kowsari, M Payami, R Amini.Task-specific ionic liquids as a new green inhibitor of mild steel corrosion[J].Applied Surface Science,2014, 289:478-486.[16] 赵 琪.含氮杂环化合物对钢铁缓蚀性能的研究[D].济南大学,2012.[17] 张启波,华一新.咪唑离子液体对铜在硫酸溶液中的缓蚀作用[J].物理化学学报,2011, 27 (3):655-663.[18] Natalya V, Likhanova,Marco A,et al.The effect of ionic liquids with imidazolium and pyridinium cations on the corrosion inhibitor of mild steel in acidic environment[J].Corrosion Science,2010,52:2 088-2 097.[19] 崔美红. 含炔基离子液体的合成及性质[D].济南大学,2012.[20] Xin Zhou, Huaiyu Yang, Fuhui Wang.[BMIM]BF4 ionic liquids as effective inhibitor for carbon steel in alkaline chloride solution[J].Electrochimica Acta,2011,56:4 268-4 275.[21] 何捍卫,胡岳华,黄可龙.铜在苯并三唑抛光液中的抛光速率及其影响因素[J].半导体技术,2002,(7):46-48.[22] 汪的华.甘复兴,姚禄安.缓蚀剂吸附行为研究进展与展望[J].材料保护,2000,(1):35-37.[23] 郑家 ,黄魁元.缓蚀剂科技发展历程的回顾与展望[J].材料保护,2000,(5):23-25.
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