Research on photocatalytic degradation of roxithromycin by graphene based S doped TiO2
Luo Xiao1, Hao Tongyao1, Zhao Yan2,Yue Lin1
1.College of Environmental Science and Engineering of Hebei University of Science and Technolgy, Pollution Prevention and Control Biotechnology Laboratory of Hebei Province, Shijiazhuang 050000, China;2.Hebei Yipin Pharmaceutical Corporation Ltd., Shijiazhuang 050000, China
In order to degrade roxithromycin in wastewater, S-TiO2 were prepared by wet method (calcining at a certain ratio of TiO2 and thiourea), and loaded onto the graphene (RGO), the photocatalyst of S doped TiO2 and graphene composites (S-TiO2-RGO) was obtained. The structure of photocatalyst was characterized by transmission electron microscopy(TEM), scanning electron microscopy(SEM), X ray diffraction (XRD) and UV vis diffuse scattering. With xenon lamp as light source and S-TiO2-RGO as photocatalyst, roxithromycin in wastewater was degraded. The results show that when the photocatalyst dosage was 500 mg / L, pH=4, reaction time was 210 min, the initial concentration of wastewater was 100 mg / L, roxithromycin degradation rate can reach 91.6%. The photocatalytic mechanism of S-TiO2-RGO was explored by adding holes and the trapping agent of ·OH.
罗 晓,郝彤遥,赵 彦,岳 琳. 石墨烯基S掺杂TiO2光催化降解罗红霉素的研究[J]. 煤炭与化工, 2016, 39(10): 1-7.
Luo Xiao, Hao Tongyao, Zhao Yan,Yue Lin. Research on photocatalytic degradation of roxithromycin by graphene based S doped TiO2. CCI, 2016, 39(10): 1-7.
[ 1 ] Wollenberger L,Halling-Sorensen B, Kusk K O. Acute and
Chronic toxicity of Veterinary Antibiotics to Daphnia magna[J].
Chemosphere, 2000, 40(7): 723-730.
[ 2 ] 尤玉静,卢格斯特,岑 立,等. 磁性碳纳米管基催化剂TiO2
/CNT S光降解氨比西林抗生素水溶液的研究[J].应用化工,
2012,41 (12):2 180-2 182.
[ 3 ] 傅 玲,刘洪波,邹艳红,等.Hummer S法制备氧化石墨
时影响氧化程度的工艺因素研究[J].炭素,2005,(4):
10-14.
[ 4 ] Hummer W S,Offeman R E.Preparation of graphitic oxide[J].
Am Chem Soc,1958,80:1 339.
[ 5 ] Alzamani M,Shokuhfar A,Eghdam E,et al.Sol-gel
fabrication and enhanced optical properties,photocatalysis,
and surface wettbaility of nanostructured titanium dioxide films
[J].Materials Science in Semiconductor Processing,2013,16
(4):1 063-1 069.
[ 6 ] Sakthivel S,Janczarek M,Kisch H. Visible Light Activity and
Photoelectrochemical Properties of Nitrogen-Doped TiO2[J]. J Phys
Chem B 2004,108(50):19 384-19 387.
[ 7 ] Williams G, Seger B, Kamat P.V. TiO2-graphene nanocomposites.
UV-assisted photocatalytic reduction of graphene oxide[J]. American
chemical society Nano,2008,2(7): 1 487-1 491.
[ 8 ] 何丽明,张慧文,曾晓晖.紫外分光光度法测定罗红霉素胶囊
的含量[J]. 广东药学院学报,2004, 20(5):475-477.
[ 9 ] 张喜瑞. 罗红霉素原料的含量测定[J].化工中间体,2015(3):
50-51.
[10] Agers Y, Bruun M S, Dalsgaard I, et al. The tetracycline resistance
gene tet (E) is frequently occurring and present on large horizontally
transferable plasmids in Aeromonas, spp. from fish farms[J].
Aquaculture, 2007, 266(1-4):47-52.
[11] Wilcks A, Hoek A H A M V, Joosten R G, et al. Persistence of DNA
studied in different ex vivo and in vivo rat models simulating the
human gut situation[J]. Food & Chemical Toxicology, 2004, 42
(3):493-502.
[12] Jakobsen L, Sandvang D, Hansen L H, et al. Characterisation,
dissemination and persistence of gentamicin resistant Escherichia
coli, from a Danish university hospital to the waste water
environment [J]. Environment International, 2008, 34(1):108-115.
[13] T HISATOMI, J KUBOTA, K DOMEN. Recent advances in
emiconductors for photocatalytic and photoelectrochemical water
splitting[J]. Chemical Society Reviews, 2014, 43(22): 7 520-7 535.
[14] J BURSCHKA, N PELLET, S J MOON, et al. Sequential deposition
as a route to high-performance perovskite-sensitized solar cells[J].
Nature, 2013, 499(7458): 316.
[15] Y SHIRAISHI, T HIRA. Selective organic transformation on
titanium oxide-based photocatalysts[J]. Journal of Photochemistry
and Photobology C-Photochemistry Reviews, 2008, 9 (4): 157-170.