吸附法捕集CO2的研究进展
胡伟康,段 硕,张永健
河北工程大学 矿业与测绘工程学院,河北 邯郸 056000
Research progress on capture of carbon dioxide from high humidity flue gas by pressure swing adsorption
Hu Weikang, Duan Shuo, Zhang Yongjian
Hebei University of Engineering, School of Mining and Mapping Engineering, Handan 056000, China
摘要 近年来,全球各地均出现了CO2排放量超标的问题。吸附法具有能耗低、设备简单、再生性能好、工艺清洁等优点,是公认捕集CO2最有效的方法。吸附剂作为吸附法的核心,介绍了沸石、金属有机骨架、活性炭、生物炭、新型复合材料等CO2吸附剂的研究进展,及未来的研究方向。随着开发更高效、成本更低的吸附剂,对降低温室效应有重要意义。
关键词 :
CO2捕集 ,
沸石 ,
金属有机骨架 ,
活性炭 ,
生物炭 ,
新型复合材料
Abstract :In recent years, CO2 emissions have exceeded the standard all over the world. Adsorption method has the advantages of low energy consumption, simple equipment, good regeneration performance and clean process, and is recognized as the most effective method for CO2 capture. Adsorbents are the core of the adsorption method. The research progress and future research direction of CO2 adsorbents was introduced such as zeolite, metal organic framework, activated carbon, biochar and new composite materials. With the development of more efficient and lower cost adsorbent, It is of great significance to reduce the greenhouse effect.
Key words :
CO2 capture
zeolite
metal organic skeleton
activated carbon
biochar
new composite materials
作者简介 : 胡伟康( 1999— ),男,江西抚州人,在校硕士研究生。
[ 1 ] 唐进京,鲁军辉,李俊明,等. CO2/H2O吸附分离特性研究[ J ]. 中国电机工程学报,2022,42( 6 ):2 216 - 2 227.
[ 2 ] Madhu Jayaprakash, Santhanam Agilan, Natarajan Muthukumara-
samy, et al. CO2 adsorption performance of template free zeolite A and X synthesized from rice husk ash as silicon source.[ J ]. RSC advances, 2022, 12( 36 ): 2 220 - 2 232.
[ 3 ] 孙 锋,王晨阳,罗 聪,等. 合成NaY型沸石的CO2吸附特性[ J ]. 洁净煤技术,2021,27( 3 ):225 - 231.
[ 4 ] Wang Jian, Zhou Yunlong, Hu Xiaotian. Adsorption of CO2 by a novel zeolite doped amine modified ternary aerogels[ J ]. Environmental research, 2022( 214 ): 2.
[ 5 ] 张丙凯,刘 晶,王敏俊,等. CO2在金属有机骨架材料M-MOF-74的吸附机理[ J ]. 燃烧科学与技术,2014,20( 3 ):252 - 256.
[ 6 ] Dong Kyu Yoo, Nazmul Abedin Khan,Sung Hwa Jhung. Polyanili-
ne-loaded metal-organic framework MIL-101(Cr): Promising adsorbent for CO2 capture with increased capacity and selectivity by polyaniline introduction[ J ]. Journal of CO2 Utilization, 2018( 28 ): 630 - 645.
[ 7 ] Lei Lei, Cheng Yan, Chen Changwei, et al. Taming structure and modulating carbon dioxide (CO2) adsorption isosteric heat of nickel-based metal organic framework (MOF-74(Ni)) for remarkable CO2 capture[ J ]. Journal of Colloid And Interface Science, 2022( 612 ):2 230 - 2 241.
[ 8 ] 段 岐. MOF-74衍生炭材料的合成与二氧化碳吸附性能研究[ D ]. 长春:长春工业大学,2022.
[ 9 ] Volker Presser, John McDonough,Sun-Hwa Yeon, et al. Effect of pore size on carbon dioxide sorption by carbide derived carbon[ J ]. Energy & environmental science: EES, 2011, 4( 8 ):221 - 236.
[ 10 ] 陈艺兰,钟琴华,曾炜鹏,等. 超临界氨水改性活性炭及其对CO2的吸附性能[ J ]. 化工环保,2021,41( 5 ):642 - 646.
[ 11 ] 郭 超,王慧琴,袁琴琴,等. 煤基含硫活性炭的制备及其CO2吸附性能[ J ]. 煤炭转化,2020,43( 4 ):58 - 65.
[ 12 ] Jin Chen, Sun Jian, Bai Shengbin, et al. Sawdust wastes-derived porous carbons for CO2 adsorption (Part 2). Insight into the CO2 adsorption enhancement mechanism of low-doping of microalgae[ J ]. Journal of Environmental Chemical Engineering, 2022, 10( 5 ): 210 - 231.
[ 13 ] Chen Guanghui, Wang Fei, Wang Shougui, et al. Facile fabrication of copper oxide modified activated carbon composite for efficient CO2 adsorption[ J ]. Korean Journal of Chemical Engineering, 2021, 38( 1 ): 212 - 229.
[ 14 ] Wu Meng, Li Xiang, Liu Wei, et al. Targeting application of hiera-
rchical porous carbon by facile one-step site-specific activation of wood powder: CO2 adsorption and supercapacitors[ J ]. Journal of Electroanalytical Chemistry, 2022( 920 ): 230 - 242.
[ 15 ] 田 秾. 基于CO2脱除的酒糟基活性炭的制备[ D ].包头: 内蒙古科技大学,2021.
[ 16 ] Wu Runping, Ye Qing,Wu Kai, et al. Highly efficient CO2 adsorpt
ion of corn kernel-derived porous carbon with abundant oxygen functional groups[ J ]. Journal of CO2 Utilization, 2021( 51 ): 113 - 125.
[ 17 ] 张 莉. 甘蔗渣活性炭的制备及其CO2吸附性能研究[ D ]. 武汉:武汉科技大学,2019.
[ 18 ] 马 荣. 生物炭基CO2吸附剂的制备及CO2吸附性能研究[ D ]. 银川:宁夏大学,2019.
[ 19 ] Melouki R, Ouadah A, Llewellyn P L. The CO2 adsorption behavior study on activated carbon synthesized from olive waste[ J ]. Journal of CO2 Utilization, 2020, 42(6 430): 101 - 292.
[ 20 ] 赵 阳,高建民,郝新敏,等. 基于KOH活化法的核桃壳基活性炭制备及其表征[ J ]. 安全与环境学报,2016,16( 2 ):262 - 266.
[ 21 ] 朱冬莹. ZIF-8与生物质组装共炭化制备炭基CO2吸附剂[ D ]. 长春:长春工业大学,2021.
[ 22 ] 饶琳莉. 低温氨基钠活化制备氮掺杂多孔炭材料及其CO2吸附性能研究[ D ]. 杭州:浙江师范大学,2020.
[ 23 ] Chen Jiachuan, Zhang Lei, Yang Guihua, Wang Qiang, Li Rui, L-
ucia Lucian A.. Preparation and Characterization of Activated Carbon from Hydrochar by Phosphoric Acid Activation and its Adsorption Performance in Prehydrolysis Liquor[ J ]. BioResourc-
es, 2017, 12( 3 ): 212 - 230.
[ 24 ] 丁 帅. 改性海藻焦吸附脱除烟气中二氧化碳的研究[ D ]. 江苏大学,2020.
[ 25 ] 浦秋芸. 生物质基活性炭复合材料的制备及其CO2吸附性能研究[ D ]. 昆明:昆明理工大学,2021.
[ 26 ] Song Caicheng, Ye Wanyue, Liu Yingcen, et al. Facile Preparation of Porous Carbon Derived from Industrial Biomass Waste as an Efficient CO2 Adsorbent. [ J ]. ACS omega, 2020, 5( 43 ): 119 - 130.
[ 27 ] Wang Shuoyu, Liu Haorui, Chen Shuixia. A strategy to synthesis amine-functional Poly(Divinylbenzene)HIPEs with controllable porous structure for effective CO2 adsorption[ J ]. Fuel, 2022( 322 ): 2 230 - 2 245.
[ 28 ] Wu Kai, Ye Qing,Wang Lanyang,Meng Fanwei, Dai Hongxing. Po-
lyethyleneimine-modified layered double hydroxide/SBA-15 composites: A novel kind of highly efficient CO2 adsorbents[ J ]. Applied Clay Science, 2022( 229 ): 1 320 - 1 340.
[ 29 ] Sun Jinqiang,Shang Mengge, Zhang Minna, Yu Shimo, Yuan Zhi-
peng, Yi Xibin, Filatov Serguei, Zhang Jing. Konjac glucomannan/cellulose nanofibers composite aerogel supported HKUST-1 for CO2 adsorption[ J ]. Carbohydrate Polymers, 2022( 293 ): 1 120 - 1 139.
[1]
柳 龙,席婧茹. 多层吸附床层中活性炭对烷烃的吸附特性 [J]. 煤炭与化工, 2023, 46(1): 137-140,160..
[2]
齐亚鹏. 减少青霉素类产品可见异物的工艺改进 [J]. 煤炭与化工, 2022, 45(7): 133-135.
[3]
赵晓胜1,周自成1,王 倩2,徐 美1,庞亚恒1,孔令伟1. 油页岩灰基NaX型沸石的合成及表征 [J]. 煤炭与化工, 2022, 45(7): 145-149,160..
[4]
李 斌. UV光催化-活性炭法处理煤化工污水废气的研究 [J]. 煤炭与化工, 2022, 45(6): 158-160.
[5]
傅修军. 高碘低灰煤基活性炭的制备及性能研究 [J]. 煤炭与化工, 2022, 45(10): 122-124,149..
[6]
张翠红,李 江,陈志敏,郭丽君. 铋基碘氧化物/活性炭制备及光催化活性研究 [J]. 煤炭与化工, 2021, 44(3): 143-146.
[7]
古 玉. 腐殖酸改性小龙虾壳生物炭对水中亚甲基蓝的吸附去除 [J]. 煤炭与化工, 2021, 44(10): 154-160.
[8]
胡 莹. 活性炭再生技术研究与发展 [J]. 煤炭与化工, 2018, 41(4): 136-139.
[9]
傅修军,陈志勇,苏景裕,王 楠. 脱H2S用活性炭的制备及样品性能研究 [J]. 煤炭与化工, 2018, 41(10): 142-145.
[10]
申宏丹,孙开进,项东升,颜淑芹. 活性炭吸附硝基苯乙酮同分异构体的研究 [J]. 煤炭与化工, 2017, 40(7): 19-21,152.
[11]
吴 超,傅修军,郑 环,李 强,牛翰彬. 煤基载银活性炭的制备及性能研究 [J]. 煤炭与化工, 2017, 40(11): 49-52.
[12]
周鹏飞,王子杰,张 硕,孙 洲. 凹凸棒土-稻壳活性炭复合滤料与陶粒滤料对水中亚甲基蓝的吸附性能研究 [J]. 煤炭与化工, 2017, 40(10): 11-15.
[13]
胡 洁,杨玉敏. 脱除脱盐废水中钙镁离子的研究 [J]. 煤炭与化工, 2016, 39(11): 98-101.
[14]
王子源. Friedel-Crafts羟烷基化反应的研究 [J]. 煤炭与化工, 2015, 38(6): 98-100.
[15]
史建春,张 鹏,李 雪,梁伟朝,张微微,杨 昆. 离子液体、镧双改性菌渣活性炭吸附—催化氧化二氧化硫研究 [J]. 煤炭与化工, 2015, 38(12): 25-27,76.