Fenton技术在水处理中的应用研究进展

摘要
图/表
参考文献(0)
相关文章 (15)

全文: PDF (0 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要

Fenton技术因具有氧化能力强、反应迅速、成本低、操作简单等优点，逐渐成为一种广泛应用的高级氧化技术。介绍了物理辅助型Fenton技术及催化型Fenton技术的特性及在水处理中应用的研究进展，重点剖析了非均相Fenton体系的优缺点，并综述了各类非均相催化剂的研究现状，旨在揭示各类Fenton技术的特征及降解有机污染物的重要意义，并对Fenton技术的优缺点及发展前景进行了总结和展望。

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	牛建瑞1
	2
	李宗泽1
	2
	李文亚1
	2
	刘艳芳1
	2
	李再兴1
	2

关键词 ：物理辅助, 催化, Fenton技术, 研究现状, 展望

Abstract：

Fenton technology is one of the advanced oxidation technologies, which has gradually been widely used, because of the advantages of strong oxidation ability, quick response, low cost, simple operation, etc.. The property and research progress in water treatment of physical assistant Fenton technology and catalytic Fenton technology were introduced, and the advantages and disadvantages of heterogeneous Fenton, and different research status of heterogeneous catalysts were mainly reviewed，thereby revealing the property of different kinds of Fenton technology and the important significance of degrading organic pollutant. The advantages and disadvantages of Fenton technology and the development foreground were summarized and prospected.

Key words： physical assistant catalytic Fenton technology research status prospect

基金资助:

牛建瑞-16博士科研基金（1181205）

通讯作者: 李再兴。E-mail：li-zaixing@163.com

作者简介: 牛建瑞（1987—），男，河北鹿泉人，讲师。E-mail：njrhepjs@163.com

引用本文:

牛建瑞1,2，李宗泽1,2，李文亚1,2，刘艳芳1,2，李再兴1,2. Fenton技术在水处理中的应用研究进展[J]. 煤炭与化工, 2016, 39(12): 71-75,147.

链接本文:

http://www.mtyhg.com.cn/CN/ 或 http://www.mtyhg.com.cn/CN/Y2016/V39/I12/71

[1] Gu Lin, Nie Jun-Ying, Zhu Nan-wen, et al. Enhanced Fenton's degradation of real naphthalene dye intermediate wastewater containing 6-nitro-1-diazo-2-naphthol-4-sulfonic acid: A pilot scale study[J]. Chemical Engineering Journal, 2012,189: 108-116.
[2] Ma Jiahai, Song Wenjing, Chen Chuncheng, et al. Fenton degradation of organic compounds promoted by dyes under visible irradiation[J]. Environmental science & technology, 2005,39(15):
5 810-5 815.
[3] Neyens E, Baeyens J. A review of classic Fenton’s peroxidation as an advanced oxidation technique[J]. Journal of Hazardous materials, 2003,98(1): 33-50.
[4] Burrows H D, Santaballa J A, Steenken S. Reaction pathways and mechanisms of photodegradation of pesticides[J]. Journal of photochemistry and photobiology B: Biology, 2002,67(2): 71-108.
[5] Zepp Richard G, Faust Bruce C, Hoigne Juerg. Hydroxyl radical formation in aqueous reactions (pH 3-8) of iron (II) with hydrogen peroxide: the photo-Fenton reaction[J]. Environmental Science & Technology, 1992,26(2): 313-319.
[6] Kiwi J, Pulgarin C, Peringer P. Effect of Fenton and photo-Fenton reactions on the degradation and biodegradability of 2 and 4-nitrophenols in water treatment[J]. Applied Catalysis B: Environmental, 1994,3(4): 335-350.
[7] Nedoloujko Alexei, Kiwi John. Parameters affecting the homogeneous and heterogeneous degradation of quinoline solutions in light-activated processes[J]. Journal of Photochemistry and Photobiology A: Chemistry, 1997,110(2): 149-157.
[8] Jiaz, Zhang W C, Wang W M, et al. Amorphous Fe78Si9B13 alloy: An efficient and reusable photo-enhanced Fenton-like catalyst in degradation of cibacron brilliant red 3B-A dye under UV–vis light[J]. Applied Catalysis B: Environmental, 2016,192: 46-56.
[9] Li Huiyuan, Priambodo Ricky, Wang Yan, et al. Mineralization of bisphenol A by photo-Fenton-like process using a waste iron oxide catalyst in a three-phase fluidized bed reactor[J]. Journal of the Taiwan Institute of Chemical Engineers, 2015,53: 68-73.
[10] Aaron Jean Jacques, Oturan Mehmet A. New photochemical and electrochemical methods for the degradation of pesticides in aqueous media. Environmental applications[J]. Turkish Journal of Chemistry, 2001,25(4): 509-520.
[11] Nidheesh P V, Gandhimathi R. Trends in electro-Fenton process for water and wastewater treatment: an overview[J]. Desalination, 2012,299: 1-15.
[12] Chen Wen-Shing, Lin Sheng-Zhi. Destruction of nitrotoluenes in wastewater by electro-Fenton oxidation[J]. Journal of hazardous materials, 2009,168(2): 1 562-1 568.
[13] 肖   华, 周荣丰. 电芬顿法的研究现状与发展[J]. 上海环境科学, 2004(6): 253-256.
[14] Nidheesh P V, Gandhimathi R. Removal of Rhodamine B from aqueous solution using graphite–graphite electro-Fenton system[J]. Desalination and Water Treatment, 2014,52(10-12): 1 872-1 877.
[15] 樊   杰, 曾   萍, 张盼月, 等. Fenton-超声联合处理金刚烷胺制药废水[J]. 环境工程学报, 2014(5): 1 744-1 748.
[16] Hou Liwei, Wang Liguo, Royer Sébastien, et al. Ultrasound-assisted heterogeneous Fenton-like degradation of tetracycline over a magnetite catalyst[J]. Journal of Hazardous Materials, 2016,302: 458-467.
[17] 徐科峰, 李   忠, 魏   帅, 等. 微波对Fenton试剂降解苯酚反应活化能的影响[J]. 华南理工大学学报(自然科学版), 2005(12): 5-9.
[18] 李国生, 颜   杰, 唐   楷, 等. 微波强化Fenton氧化法对老龄垃圾渗滤液的处理试验[J]. 净水技术, 2011(3): 38-43.
[19] Zhang Xuhong, Chen Yanzhuo, Zhao Ning, et al. Citrate modified ferrihydrite microstructures: facile synthesis, strong adsorption and excellent Fenton-like catalytic properties[J]. RSC Advances, 2014,4(41): 21 575-21 583.
[20] Parsons Simon. Advanced oxidation processes for water and wastewater treatment[J]. Water Intelligence Online, 2005(4):
21 398-70 084.
[21] Liu Hui, Wang Yan, Ma Yan, et al. The microstructure of ferrihydrite and its catalytic reactivity[J]. Chemosphere, 2010,79(8): 802-806.
[22] Wu Yongjuan, Chen Rufen, Liu Hui, et al. Feasibility and mechanism of p-nitrophenol decomposition in aqueous dispersions of ferrihydrite and H2O2 under irradiation[J]. Reaction Kinetics, Mechanisms and Catalysis, 2013,110(1): 87-99.
[23] Cao Zhiqin, Qin Mingli, Jia Baorui, et al. One pot solution combustion synthesis of highly mesoporous hematite for photocatalysis[J]. Ceramics International, 2015,41(2): 2 806-2 812.
[24] Teixeira Luiz Alberto Cesar, Vieira Junior Nildo De Abreu, Yokoyama Lidia, et al. Degradation of phenol in mine waters using hydrogen peroxide and commercial steel wool[J]. International Journal of Mineral Processing, 2015,138: 15-19.
[25] Wang Nannan, Zheng Tong, Zhang Guangshan, et al. A review on Fenton-like processes for organic wastewater treatment[J]. Journal of Environmental Chemical Engineering, 2016,4(1): 762-787.
[26] Hu Xiaobin, Liu Benzhi, Deng Yuehua, et al. Adsorption and heterogeneous Fenton degradation of 17α-methyltestosterone on nano Fe3O4/MWCNTs in aqueous solution[J]. Applied Catalysis B: Environmental, 2011,107(3): 274-283.
[27] Costa Regina C, Lelis M F , Oliveira L C A, et al. Novel active heterogeneous Fenton system based on Fe3-xMxO4 (Fe, Co, Mn, Ni): The role of M2+ species on the reactivity towards H2O2 reactions[J]. Journal of Hazardous Materials, 2006,129(1–3): 171-178.
[28] Rahim Pouran Shima, Abdul Aziz A R, Wan Daud Wan Mohd Ashri, et al. Estimation of the effect of catalyst physical characteristics on Fenton-like oxidation efficiency using adaptive neuro-fuzzy computing technique[J]. Measurement, 2015,59: 314-328.
[29] Hassan H, Hameed B H. Fe–clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4[J]. Chemical Engineering Journal, 2011,171(3): 912-918.

30] Sun Sheng-Peng, Lemley Ann T. p-Nitrophenol degradation by a heterogeneous Fenton-like reaction on nano-magnetite: process optimization, kinetics, and degradation pathways[J]. Journal of
Molecular Catalysis A: Chemical, 2011,349(1): 71-79.
[31] Carriazo J G, Guelou E, Barrault J, et al. Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays[J]. Applied Clay Science, 2003,22(6): 303-308.
[32] Centi Gabriele, Perathoner Siglinda, Torre Teresa, et al. Catalytic wet oxidation with H2O2 of carboxylic acids on homogeneous and heterogeneous Fenton-type catalysts[J]. Catalysis Today, 2000,55(1): 61-69.
[33] Kochetkova R. P, Babikov A F, Shpilevskaya L I, et al. Liquid phase catalytic oxidation of phenol[J]. Chemistry and Technology of Fuels and Oils, 1992,28(4): 225-229.
[34] Nidheesh P V. Heterogeneous Fenton catalysts for the abatement of organic pollutants from aqueous solution: a review[J]. Rsc Advances, 2015,5(51): 40 552-40 577.
[35] Sekaran G, Karthikeyan S, Boopathy R, et al. Response surface modeling for optimization heterocatalytic Fenton oxidation of persistence organic pollution in high total dissolved solid containing wastewater[J]. Environmental Science and Pollution Research, 2014,21(2): 1 489-1 502.
[36] Karthikeyan S, Priya M. Ezhil, Boopathy R, et al. Heterocatalytic Fenton oxidation process for the treatment of tannery effluent: kinetic and thermodynamic studies[J]. Environmental Science and Pollution Research, 2012,19(5): 1 828-1 840.
[37] Huang Hsu-Hui, Lu Ming-Chun, Chen Jong-Nan. Catalytic decomposition of hydrogen peroxide and 2-chlorophenol with iron oxides[J]. Water Research, 2001,35(9): 2 291-2 299.
[38] 邓景衡, 文湘华, 李佳喜. 碳纳米管负载纳米四氧化三铁多相类芬顿降解亚甲基蓝[J]. 环境科学学报, 2014(6): 1 436-1 442.
[39] Nguyen Thi Dung, Phan Ngoc Hoa, Do Manh Huy, et al. Magnetic Fe2MO4 (M: Fe, Mn) activated carbons: fabrication, characterization and heterogeneous Fenton oxidation of methyl orange[J]. Journal of Hazardous Materials, 2011,185(2): 653-661.
[40] Soon Ai Ni, Hameed B. H. Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process[J]. Desalination, 2011,269(1): 1-16.
[41] Ghosh Prabir, Kumar Chandra, Samanta Amar Nath, et al. Comparison of a new immobilized Fe3+ catalyst with homogeneous Fe3+–H2O2 system for degradation of 2, 4‐dinitrophenol[J]. Journal of Chemical Technology and Biotechnology, 2012,87(7): 914-923.
[42] Bautista Patricia, Mohedano Angel F, Casas Jose A, et al. Highly stable Fe/γ‐Al2O3 catalyst for catalytic wet peroxide oxidation[J]. Journal of chemical technology and biotechnology, 2011,86(4): 497-504.
[43] Zhong Xin, Royer Sebastien, Zhang Hui, et al. Mesoporous silica iron-doped as stable and efficient heterogeneous catalyst for the degradation of CI Acid Orange 7 using sono–photo-Fenton process[J]. Separation and purification technology, 2011,80(1): 163-171.
[44] 吕树祥, 魏佳, 胡炀, 等. Fe-ZSM-5分子筛催化剂催化降解高浓度含酚废水[J]. 过程工程学报, 2008(4): 751-755.
[45] 何炽, 赵景联, 夏敏强, 等. 分子筛固载Fe~(2+)-Fenton法降解水中甲基橙的研究[J]. 环境科学与技术, 2006(12): 1-3.
[46] Yan Ying, Jiang Songshan, Zhang Huiping, et al. Preparation of novel Fe-ZSM-5 zeolite membrane catalysts for catalytic wet peroxide oxidation of phenol in a membrane reactor[J]. Chemical Engineering Journal, 2015,259: 243-251.
[47] Martínez Fernando, Melero Juan Antonio, Botas Juan ?魣ngel, et al. Treatment of phenolic effluents by catalytic wet hydrogen peroxide oxidation over Fe2O3/SBA-15 extruded catalyst in a fixed-bed reactor[J]. Industrial & engineering chemistry research, 2007,46(13): 4 396-4 405.
[48] Yang Sheng-Tao, Zhang Wu, Xie Jingru, et al. Fe3O4@SiO2 nanoparticles as a high-performance Fenton-like catalyst in a neutral environment[J]. RSC Advances, 2015,5(7): 5 458-5 463