Research on Treatment Methods of Oxytetracycline Wastewater
JIANG Guo-ping1, ZHAO Jun-na2, LI Gui-xia2, YANG Lan3, GAO Xiang2, GENG Xiao-ling2, LI Zai-xing2
1. Jiangsu Fengyuan Bioengineering Corporation Ltd., Yancheng 224300, China; 2. School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China; 3. Hebei Institute of Food Quality Supervision, Inspection and Research, Shijiazhuang 050091, China
China is one of the countries in which the production and usage amount of the antibiotics are very large. And in the antibiotics,oxytetracycline is one class of tetracycline antibiotics used most widely and the usage is the largest. Because the pollutant concentration was high and the composition of pollutant was complex, oxytetracycline wastewater was classified as the high concentration refractory organic wastewater,the reasonable and effective treatment technologies of oxytetracycline wastewater has got more and more attention. The characteristics and progress of physico-chemical treatment technology, biological treatment technology, and the advanced treatment technology for oxytetracycline wastewater were reviewed. It was put forward that the key research direction of oxytetracycline wastewater treatment was strengthening the depth treatment of oxytetracycline wastewater in order to achieve the discharge standard.
[ 1 ] 剧盼盼.微波-Fenton氧化法深度处理土霉素废水试验研究[ D ].石家庄:河北科技大学,2012.
[ 2 ] 李再兴,剧盼盼,左剑恶,等.微电解/Fenton法深度处理土霉素的研究[ J ].中国给水排水,2012,28(5):74 - 77.
[ 3 ] Roman H, Thomas T, Klaus H. Occurrence of antibiotics on the aquatic environment[ J ]. Science of the Total Environment, 1999, 225: 109-118.
[ 4 ] Kathryn D B, Jerzy K, Bruce T, et al. Occurence of antibiotics in hospital, residential, and dairy effluent, municipal wasterwater, and the Rio Grande in New Mexico[ J ]. Science of the Total Environment, 2006, 36( 6 ): 772 - 783.
[ 5 ] Hirsch R, Ternes T, Haberer K. Occurrence of antibiotics in the aquatic environment[ J ]. The Science of the Total Environment, 1999, 225(1-2): 109 - 118.
[ 6 ] Ben W W, Qiang Z M, Adams C, et al. Simultaneous determination of sulfonamides, tetracyclines and tiamulin in swine wastewater by solid-phase extraction and liquid chromatography-mass spectrometry [ J ]. Journal of Chromatography A, 2008, 1 202(2): 173 - 180.
[ 7 ] 徐武军,张国臣,郑明霞,等.臭氧氧化技术处理含抗生素废水[ J ].化学进展,2010,2(5):1 002 - 1 009.
[ 8 ] 张向怡,孙宝盛,王庆生,等. 离子交换法回收土霉素及废水处理的研究[ J ].工业水处理,2006,26(2):74 - 77.
[ 9 ] 刘转年,金奇庭,周安宁.废水的吸附法处理[ J ].水处理技术,2003,29(6):318 - 322.
[10] 马子川,张素坤,王靖飞,等.新生态MnO2处理土霉素生产废水的实验研究[ J ].环境与开发,2001(4):33 - 34.
[11] 唐受印,汪大晕.废水处理工程[ M ].北京:化学工业出版社,1998.
[12] 魏有权,王化军,张 强,等.气浮法预处理土霉素废水的试验研究[ J ].过滤与分离,2003,13(1):19 - 37.
[13] 王辉宇,李立明,李敬国.上流式污泥床反应器处理抗生素废水试验[ J ].华北水利水电学院学报,2002, 23(3):66 - 68.
[14] 范永哲,戚 鹏,赵仁兴.水解酸化法预处理青霉素、土霉素废水实验研究[ J ].环境保护科学,2002,28(114):19 - 21.
[15] 胡晓东,胡冠民,景有海.SBR法处理高浓度土霉素废水的试验研究[ J ].给水排水,1995,32(7):21 - 22.
[16] 陈 鲲,张清霞,李 跃.连续性循环式活性污泥法在土霉素类制药废水处理中的应用[ J ].河南农业大学学报,2002,36(3):22 - 25.
[17] Sponza D T, Celebi H. Removal of Oxytetracycline (OTC) in a synthetic pharmaceutical wastewater by a sequential Anaerobic Multichamber Bed Reactor(AMCBR)/Completely Stirred Tank Reactor(CSTR) System: Biodegradation and Inhibition Kinetics[ J ]. Bioresource Technology, 2012, 104: 100 - 110.
[18] 王培京,刘战宇,葛 平. 厌氧-好氧两级生化法处理土霉素生产废水[ J ]. 环境工程,2003,21(1):27 - 29.
[19] 朱新锋,张乐观. 铁炭微电解-Fenton-生物接触氧化法处理土霉素废水[ J ].水处理技术,2010,36(2):109 - 111.
[20] 梁存珍,杨 敏,马文林,等.水解酸化-反硝化-硝化组合工艺处理土霉素废水的效果[ J ].环境科学,2005,26(1):127 - 129.
[21] 李再兴,剧盼盼,左剑恶,等. 微电解/Fenton法深度处理土霉素废水的研究 [ J ].中国给水排水,2012,28(5):74 - 77.
[22] 苟世霞,王春荣,于晓华,等.Photo-Fenton高级氧化技术处理土霉素废水的研究[ J ].甘肃科学学报,2013,25(3):43 - 46.
[23] Sakthivel S, Shankar M V, Palanichamy M. Enhancement of photocatalytic activity by metal deposition characterization and photonic efficiency of Pt/Au and deposition on TiO2 catalyst[ J ]. Water Research, 2004, 38(13):3 001-3 008.
[24] LUO H M, Takata T, Lee Y, et al. Photocatalytic activity enhancing for titanium dioxide by co-doping with bromine and chlorine[ J ]. Chemistry of Materials, 2004, 16(5): 846 - 849.
[25] Nukumizu K, Nunoshige J, Takata T, et al. TiNxOyFz as a stable photocatalyst for water oxidation in visible light[ J ]. Chemistry Letters, 2003, 32(2): 196 - 197.
[26] 黄丽萍,陈东辉,黄满红,等.铁碘共掺杂纳米TiO2光催化降解水中土霉素的研究[ J ].水处理技术,2011,37(5):77-80.
[27] Joаo H O S P, Vítor J P V, Maria T B, et al. Photo catalytic degradation of oxytetracycline using TiO2 under natural and simulated solar radiation[ J ]. Solar Energy, 2011, 85(11): 2 732 - 2 740.
[28] 李再兴,刘 焕,刘艳芳,等.ClO2催化氧化处理土霉素废水处理站二级出水[ J ].河北科技大学学报,2013,34(4):365 - 369.
[29] 王春平,刘清福,马子川.催化臭氧化法降解土霉素废水[ J ].工业水处理,2005,25(4):56 - 58.