基于LiPF<sub>6</sub>的锂离子电池电解液的发展现状

摘要
图/表
参考文献
相关文章 (5)

全文: PDF (0 KB) HTML (0 KB)
输出: BibTeX | EndNote (RIS)

摘要

近年来随着社会的发展和科技的进步，锂离子电池已成为重要的主流动力电池之一。分别从溶剂和添加剂2个方面综述了基于LiPF₆的锂离子电池电解液的发展现状,详细介绍了适用于锂离子电池电解液的溶剂和添加剂，应用于锂离子电池电解液的常用有机溶剂有碳酸酯类、醚类和羧酸酯类有机溶剂，添加剂以其作用目的区分，可分为SEI成膜添加剂、导电添加剂、稳定添加剂、控制水分和游离酸添加剂、抗过充添加剂、阻燃添加剂及浸润性添加剂等；展望了锂离子电池电解液的研究方向。

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	闫雅婧

关键词 ：锂离子电池电解液, LiPF₆, 溶剂, 添加剂

Abstract：

In recent years with the development of society and the advancement of technology,lithium-ion batteries have become one of the imporrtant mainstream batteries. Development status of the lithium-ion battery electrolytes based on LiPF₆ were reviewed through the solvents and additives, and the solvents and additives used in the lithium-ion battery electrolytes were introduced.The solvents used in lithium-ion battery electrolyte are common organic carbonates, carboxylic acid esters, ethers and organic solvents, and so on. According to their functions, the additives could be divided into these categories: SEI forming improver additives, conductive additives, stabilizing additives, control-water and free acid additives, overcharge protection additives, flame retardant additives, wetting additives, and so on. The researches of the lithium ion battery electrolytes were prospected.

Key words： lithium-ion battery electrolyte LiPF₆ solvent additive

作者简介: 闫雅婧（1984— ），女，河北辛集人，助理工程师。E-mail：yyj3721@126.com

引用本文:

闫雅婧. 基于LiPF₆的锂离子电池电解液的发展现状[J]. 煤炭与化工, 2013, 36(5): 28-31,41. YAN Ya-jing. Development Status of Lithium-ion Battery Electrolytes Based on LiPF₆. CCI, 2013, 36(5): 28-31,41.

链接本文:

http://www.mtyhg.com.cn/CN/ 或 http://www.mtyhg.com.cn/CN/Y2013/V36/I5/28

[ 1 ]      N Munichandraiah, L G Scanlon, R A Marsh． Surface films oflithium: an overview of electrochemical studies [ J ]． Journal of Power Sources, 1998, 72（ 2 ）： 203 - 210.

[ 2 ]      王　蓁. 几种锂离子电池及添加剂的性能研究 [　D　]．新疆大学，2008．

[ 3 ]      吴宇平，万春荣，姜长印．锂离子电池 [ M ]．北京：化学工业出版社，2002.

[ 4 ]      李伟宏，戴永年，姚耀春，等. 锂离子二次电池有机电解液研究进展 [ J ]．化工时刊， 2004，18（ 3　）：1 - 4.

[ 5 ]      王仕力．基于LiPF6的几种锂离子电池电解液的性能研究[ D ]．新疆大学，2006.

[ 6 ]     G C Chung, H J Kim, S H Jun, et al. New cyclic carbonate solvent for lithium ion battery: trans-2, 3-butylenr carbonate [ J ]. Elec-trochem. Commun. 1999，1（ 10 ）: 493 - 496.

[ 7 ]    K Yokoyama, T Sasano, A Hiwara. Fluorine-substituted cyclic carbonate electrolytic solution and battery containing the same [ P ]. US: 6010806，2000-01-04.

[ 8 ]    D P Wilkinson，J R Dahn. Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes[ P ]. US：5130211, 1992-07-14

[ 9 ]     S Herreyre, O Huchet, S Barusseau, et al. New Li-ion electrolytes for low temperature applications [ J　]. J Power Sources, 2001,97: 576 - 580．

[ 10 ]   Zhang S S.A review on electrolyte additives for lithium-ion batteries[ J ]. Power Sources,2006,162（ 2 ）:1 379 - 1 394.

[ 11 ]　禹筱元，胡国荣，刘业翔. 锂离子电池非水电解液的研究 [ J ]. 电池， 2003, 33（3 ）：177 - 180.

[ 12 ]    Wu Y P, Jiang C, Wan C, et al.Modified natural graphite as anode material for lithium ion batteries [ J ]. Power Sources,2002,111（2 ）：329 - 334.

[ 13 ]     Aurbach D, Eineli Y, Chusid O,et a1. The correlation between the surface cemistry and the performance of Li-Carbon intercalation anodes for rechargeable rocking-chair typc batteries[ J ]．Electrochemical Society,1994, 141（ 3 ）：603 - 611.

[ 14 ]    Shin J S,Hart C H,Jung U H,et a1.Effect of Li2C03 additive on gas generation in lithium-ion batteries[J]. Power Sources,2002, 109：47 - 52.

[ 15 ]    Xu K,Zhang S S,Jow R.Electrochemical impedance study of graphite/electrolyte interface formed in LiBOB/PC electrolyte　[ J ]．Power Sources,2005,143:197 - 202.

[ 16 ] Zhang S S,Xu K,Jow T R,et al.Tris（2,2,2-trifluoroethyl ）phosphite as a co-solvent for nonflammable electrolytes in li-ion batteries [ J ]. Power Sources,2003,113: 166 - 172.

[ 17 ]    Hiroi O,Hamano K,Yoshida Y,et al.Noaqueous electrolytic solution for battery and nonqueous electrolytic solution battery using the same [ P ]. US:6305540, 2001-10-23.

[ 18 ]    R Mcmillan, H Slegr,Z X Shu, et al. Fluoroethyl carbonate electrolyte and its use in lithium ion batteries with graphite anodes [ J ]. Journal of Power Sources, 1999，81：20 - 26.

[ 19 ]    贺艳兵，唐致远，宋全生，等．锂离子电池热稳定性添加剂的研究进展 [ J ].材料导报,2006,20（ 10 ）：32 - 35.

[ 20 ]    左晓希，苏达根，刘建生，等. 乙醇胺作为电解液稳定剂的研究 [ J ].电池,2005,35（ 5　）： 366 - 367.

[ 21 ]   Saidi M Y，Gao F,Barker J，et al.Additive to stabilize electro chemical cell [ P ]. US: 5846673,1998-12-08.

[ 22 ]    杨瑞甫，张宝川．二次锂离子电池电解液的制备方法及其设备[ P ]. CN:1434536A, 2003-08-06.

[ 23 ]    Yamane H,Inoue T,Fujita M,et al.A causal study of the capacity fading of Li1.01Mn1.99O4 cathode at 80 ℃and the suppressing substances of its fading　[ J ]．Power sources,2001，99: 60 - 65.

[ 24 ] 　陈　辉．锂离子电池电解液成膜添加剂的研究　[ D ]. 哈尔滨工程大学，2006.

[ 25 ] 　李   贺，孔令丽，张莹莹，等．锂离子电池电解液阻燃添加剂的研究进展[ J ]．电池技术, 2009, 33（9 ）:819 - 821.

[ 26 ] 　J Yamaki Electrochemical intercalation of lithium into a natural graphite anode in quaternary[ C ] . Journal of Electrochemical Society 204th Meeting，293.

[ 27 ]     J Arai. A new non-flammable electrolyte containing methyl nonafluorobutyl ether　for lithium secondary batteries [ J ]. Journal of the Applied Electrochemistry, 2002,32（10 ）：1 071.

[ 28 ] 　K Kim, S Ahn, H S Kim. Electrochemical and thermal properties of 2,4,6-tris（trifluoromethyl）-1,3,5-triazine as a flame retar dant additive in Li-ion batteries [ J ].Electrochemica Acta, 2009，54（8 ）：2 259 - 2 265.

[ 29 ] 　金真喜.锂离子二次电池用的电解液和包含它的锂离子二次电池 [ P ]. CN:100442592C,2008-12-10.