高级氧化技术处理抗生素废水研究进展

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摘要

抗生素废水具有浓度高、成分复杂、生物毒性大、色度高、难降解等特点，传统的生物方法很难将其去除，而高级氧化技术在抗生素废水的处理中取得了很好的效果。综述了不同高级氧化技术，Fenton氧化技术、光催化氧化技术、电化学氧化技术、超声氧化技术、臭氧氧化技术的原理、特点以及在抗生素废水处理中的实际应用，提出今后应继续深入进行高级氧化技术处理抗生素废水的动力学研究，为实际工程应用提供理论依据和技术指导，并将高级氧化技术规模化应用到抗生素废水处理中，以降低运行成本，提高效率。

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关键词 ：高级氧化技术, 抗生素废水, 废水处理, 机理

Abstract：

The antibiotic wastewater has the characteristics of high concentration, complex composition, high biological toxicity, high chroma and difficult to degrade. Advanced oxidation technologies have achieved good results in the treatment of antibiotic wastewater. The principle, characteristics and application in antibiotic wastewater treatment of different advanced oxidation technologieswhich are Fenton oxidation photocatalytic oxidation, electrochemical oxidation, ultrasonic oxidation technology and ozone oxidation technology were summarized. It is put forward the kinetic study of advanced oxidation technologies in treatment of antibiotic wastewater should be in-depth carried out in orderto provide theoretical basis for the practical engineering technology application. The advanced oxidation technologieswill beused in the treatment of antibiotic wastewater in order to reduce the operation cost and improve the efficiency.

Key words： advanced oxidation technology antibiotic wastewater wastewater treatment mechanism

基金资助:

河北省建设科学技术研究计划(2015-108)，河北省高等学校科学技术研究项目(ZD2015060)

通讯作者: 李再兴，男，河北科技大学教授。E-mail：li-zaixing@163.com

作者简介: 张智理（1992—），男，河北张家口人，硕士研究生。E-mail：1973289110@qq.com

引用本文:

张智理，刘艳芳，牛建瑞，李再兴. 高级氧化技术处理抗生素废水研究进展[J]. 煤炭与化工, 2017, 40(1): 37-39,151. Zhang Zhili1,2，Liu Yanfang1,2，Niu Jianrui1,2， Li Zaixing1,2. Research progress of advanced oxidation technologies used in the treatment of antibiotic wastewater. CCI, 2017, 40(1): 37-39,151.

链接本文:

http://www.mtyhg.com.cn/CN/ 或 http://www.mtyhg.com.cn/CN/Y2017/V40/I1/37

[ 1 ] 王福华, 王金龙.抗生素废水处理方法的研究进展[J]. 河北企业,2014(3):90-91.
[ 2 ] Li S, Li X, Wang D.Membrane (RO-UF) filtration for antibiotic wastewater treatment and recovery of antibiotics[J]. Separation and Purification Technology，2004,34(1–3):109-114.
[ 3 ] Novo A, Manaia C M.Factors influencing antibiotic resistance burden in municipal wastewater treatment plants[J]. Applied Microbiology and Biotechnology. 2010,87(3):1157-1166.
[ 4 ] 黄宏, 李圆杏, 杨红伟.水环境中抗生素的光降解研究进展[J].环境化学,2013(7):1 335-1 341.
[ 5 ] Arslan-Alaton I, Gurses F.Photo-Fenton-like and hoto-fenton-like oxidation of Procaine Penicillin G formulation effluent[J]. Journal of Photochemistry and Photobiology A:Chemistry,2004,165(1-3):165-175.
[ 6 ] 沈小华, 买文宁, 苏涛.Fenton试剂处理抗生素厌氧处理出水的试验研究[J]. 水处理技术,2010(4):79-81.
[ 7 ] 冯精兰, 师少辉, 孙剑辉.Fenton法降解抗生素磺胺间甲氧嘧啶
钠[J]. 环境工程学报,2012(9):3 125-3 130.
[ 8 ] Su R J, Wang P, Jiang L M, et al.Study on Treatment of AcetylspiramycinPharmaceutical Wastewater by the Photo-Fenton OxidationProcess[J]. Advanced Materials Research,2010,113-116:512-515.
[ 9 ] Melo S A S, Trovó A G, Bautitz I R, et al.Degradacáo de fármacos residuais por processos oxidativos avancados[J].Química Nova, 2009,32(1):188-197.
[10] 郭佳, 张渊明, 杨骏, 等.光催化氧化降解制药废水中头孢曲松钠的研究[J]. 生态科学, 2008，27(6):446-451.
[11] 左红影.光催化氧化处理半合成抗生素制药废水试验研究[J]. 广东化工, 2006，33(9):39-41.
[12] Klauson D, Babkina J, Stepanova K, et al.Aqueous photocatalytic oxidation of amoxicillin[J]. Catalysis Today,2010,151(1):39-45.
[13] Palominos R A, Mondaca M A, Giraldo A, et al.Photocatalytic oxidation of the antibiotic tetracycline on TiO2 and ZnO suspensions[J]. Catalysis Today， 2009,144(s 1-2):100-105.
[14] Jara C C, Fino D, Specchia V, et al.Electrochemical removal of antibiotics from wastewaters[J]. Applied Catalysis B Environmental,2007,70(1-4):479-487.
[15] Eleotério I C, Forti J C, de Andrade A R.Electrochemical Treatment of Wastewater of Veterinary Industry Containing Antibiotics[J]. Electrocatalysis,2013,4(4):283-289.
[16] Guo W, Shi Y, Wang H, et al.Intensification of sonochemical degradation of antibiotics levofloxacin using carbon tetrachloride[J] . Ultrasonics Sonochemistry, 2010,17(4):680-684.
[17] Su S, Guo W, Yi C, et al.Degradation of amoxicillin in aqueous solution using sulphate radicals under ultrasound irradiation[J]. Ultrasonics Sonochemistry, 2012,19(3):469-474.
[18] Hou L, Hui Z, Xue X.Ultrasound enhanced heterogeneous activation of peroxydisulfate by magnetite catalyst for the degradation of tetracycline in water[J]. Separation & Purification Technology, 2012,84(2):147-152.
[19] Hong P K, Zeng Y.Degradation of pentachlorophenol by ozonation and biodegradability of intermediates[J]. Water Research,2002,36(17):4 243-4 254.
[20] Arslan A I, Caglayan A E.Toxicity and biodegradability assessment of raw and ozonated procaine penicillin G formulation effluent[J].Ecotoxicology & Environmental Safety,2006,63(1):131-140.
[21] Khan M H, Bae H, Jung J Y.Tetracycline degradation by ozonation in the aqueous phase: proposed degradation intermediates and pathway[J]. Journal of Hazardous Materials, 2010,181(1-3):659-665.
[22] Lee H, Lee E, Lee C H, et al.Degradation of chlorotetracycline and bacterial disinfection in livestock wastewater by ozone-based advanced oxidation[J]. Journal of Industrial & Engineering Chemistry, 2011,17(3):468-473.
[23] Alaton I A, Dogruel S, Baykal E, et al.Combined chemical and biological oxidation of penicillin formulation effluent[J]. Journal of Environmental Management,2004,73(2):155-163.
[24] 赵俊娜, 李再兴, 刘艳芳, 等.Mn/γ-Al2O3催化剂的制备及头孢合成废水的催化臭氧氧化法深度处理[J]. 化工环保,2014，34(5):475-480.
[25] Gómez-Pacheco C V, Sánchez-Polo M, Rivera-Utrilla J, et al.Tetracycline removal from waters by integrated technologies based on ozonation and biodegradation[J]. Chemical Engineering Journal, 2011,178(1):115-121.
[26] Beltrán F J, Pocostales P, Alvarez P, et al.Diclofenac removal from water with ozone and activated carbon[J]. Journal of Hazardous Materials, 2009,163(2-3):768-776.
[27] Sánchez-Polo M, Rivera-Utrilla J, Prados-Joya G, et al.Removal of pharmaceutical compounds, nitroimidazoles, from waters by using the ozone/carbon system[J]. Water Research,2008,42(15):4 163-4 171.
[28] Rivera-Utrilla J, Sánchez-Polo M, Prados-Joya G, et al.Removal of tinidazole from waters by using ozone and activated carbon in dynamic regime[J]. Journal of Hazardous Materials,2009,174(1-3):880-886.