In this paper, the comprehensive geophysical prospecting method was used to study the fine delineation of the shallow goaf and water accumulation range in the south of Tian 'an Coal Industry of Jincheng Anthracite Mining Group.Due to the multi-solution problem of a single geophysical prospecting method, it could not meet the needs of comprehensive prediction application. This geophysical prospecting technology research combined the advantages of high density resistivity method to delineate abnormal areas and induced polarization method to verify abnormal areas. The two technical methods complemented and verified each other, so as to accurately obtain the distribution range of coal mine goaf and water accumulation area in goaf, and provide accurate geophysical prospecting data for mine safety production.