Abstract:In order to explore the gasification reactivity of coal with different metamorphic grades, the gasification reactivity of 11 kinds of coal with different metamorphic grades was studied by using a drop-type fixed bed reactor with CO2 as the gasification agent. The relationship between gasification reactivity and volatile matter, fixed carbon, carbon content and ash composition was investigated. The results show that there are still obvious differences in the gasification reactivity of 11 kinds of coal with different metamorphic degrees at 1 400 °C. The gasification reactivity of low metamorphic degree coal is much higher than that of medium / high metamorphic degree coal, and the time required for complete gasification reaction is 7 times higher than that of gasification reaction index. From the perspective of industrial analysis and elemental analysis, volatile matter, fixed carbon and carbon content have a good correlation with coal gasification reactivity, and the correlation coefficient is more than 0.88. From the analysis of ash composition, the correlation between alkalinity index and coal gasification reactivity is poor. Therefore, the advantages and disadvantages of coal gasification reactivity can be predicted according to the composition information of volatile matter, fixed carbon and carbon content of coal, which can provide reference for coal gasification application.
任立伟,魏蕊娣. 煤的气化反应性与其组成的关系研究[J]. 煤炭与化工, 2024, 47(2): 110-114.
Ren Liwei, Wei Ruidi. Study on the relationship between coal gasification reactivity and its composition. CCI, 2024, 47(2): 110-114.
[ 1 ] Higman C , Tam S . Advances in Coal Gasification, Hydrogenation, and Gas Treating for the Production of Chemicals and Fuels[ J ]. Chemical Reviews,2014,114( 3 ):1 673 - 1 708.
[ 2 ] 张新沙,宋旭东,苏暐光,等.宁东煤煤焦-CO2气化反应特性的原位研究[ J ]. 燃料化学学报,2019,47( 4 ):358 - 392.
[ 3 ] 王永刚,孙加亮,张 书. 反应气氛对褐煤气化反应性及半焦结构的影响[ J ]. 煤炭学报,2014,39( 8 ):1 765 - 1 771.
[ 4 ] 许修强,王永刚,陈国鹏,等. 水蒸气对褐煤原位气化半焦反应性能及微观结构的影响[ J ]. 燃料化学学报,2015,43( 5 ):546 - 553.
[ 5 ] 丁 路,周志杰,赵 冰,等. 滴管炉内不同煤阶煤焦水蒸气气化反应特性[ J ]. 化工学报,2014,65( 3 ):993 - 1 002.
[ 6 ] 余俊钦,卫俊涛,丁 路,等. 生物质灰添加对无烟煤煤焦气化特性的影响[ J ]. 燃料化学学报,2018,46( 10 ):1 161 - 1 167.
[ 7 ] Takarada T, Tamai Y, Tomita A. Reactivities of 34 coals under st-
eam gasification[ J ]. Fuel,1985,64( 10 ):1 438 - 1 442.
[ 8 ] Liwei Ren, Jianli Yang, Feng Gao, et al. Laboratory Study on Gas-
ification Reactivity of Coals and Petcokes in CO2/Steam at High Temperatures[ J ]. Energy & Fuels, 2013, 27( 9 ):5 054 -
5 068.
[ 9 ] 赵 奇. 煤对CO2的化学反应性与原煤性质的关系[ J ]. 洁净煤技术,2012,18( 3 ):74 - 77.
[ 10 ] Jing X, Wang Z, Zhang Q, et al. Evaluation of CO2 Gasification R-
eactivity of Different Coal Rank Chars by Physicochemical Properties[ J ]. Energy & Fuels, 2013, 27( 12 ):7 287 - 7 293.
[ 11 ] Zhang L, Huang J, Fang Y, et al. Gasification Reactivity and Kine-
tics of Typical Chinese Anthracite Chars with Steam and CO2[ J ]. Energy & Fuels, 2006, 20( 3 ): 1 201 - 1 210.
[ 12 ] Wu Z, Wang S, Luo Z, et al. Physico-chemical properties and gas-
ification reactivity of co-pyrolysis char from different rank of coal blended with lignocellulosic biomass: Effects of the cellulose[ J ]. Bioresource Technology, 2017, 235: 256 - 264.
[ 13 ] Wang Z H, Zhang K, Li Y, et al. Gasification characteristics of dif-
ferent rank coals at H2O and CO2 atmospheres[ J ]. Journal of Analytical & Applied Pyrolysis, 2016, 122( 11 ):76 - 83.
[ 14 ] Kim Y T, Seo D K, Hwang J. Study of the Effect of Coal Type and Particle Size on Char-CO2 Gasification via Gas Analysis[ J ]. Energy & Fuels, 2011, 25( 11 ): 5 044 - 5 054.