In order to obtain construction structural adhesives with well-balanced overall performance, the addition of appropriate amounts of additives is crucial. E-51 was employedas the epoxy matrix and a blended curing agent consisting of 201 and 650 at a mass ratio of 7∶3. The effects of reactive diluent, toughening agent, and coupling agent dosage on the mechanical properties, gel time, and toughness of epoxy-based construction structural adhesives were systematically investigated. Structural and performance characterization was performed using SEM and IR techniques. Results revealed that increasing the diluent content significantly reduced viscosity, prolonged gel time, and enhanced flowability. Tensile shear strength, flexural strength, and impact strength exhibited an initial increase followed by a decrease, whereas tensile strength and compressive strength demonstrated a declining trend. Increasing the toughening agent and coupling agent content revealed a consistent rise-fall pattern in mechanical strengths.
[ 1 ] 刘美华,李 程,刘志勇. 活性稀释剂环氧环己烷对聚酰胺-胺固化环氧树脂体系性能的影响[ J ]. 中南大学学报(自然科学版),2013,44( 2 ):522 - 524.
[ 2 ] Ho T H, Wang C S. Modification of epoxy resins by hydrosilation for electronic encapsulation application[ J ]. Journal of Applied Polymer Science, 1994, 54( 1 ): 13 - 23.
[ 3 ] 鲁红兵,余寿文,杨 卫,等. 橡胶增韧环氧树脂增韧机理的断裂力学研究[ J ]. 清华大学学报(自然科学版),1990,30( 5 ):23 - 29.
[ 4 ] Thomas R, Ding Y M, He Y L, et al. Miscibility, morphology, ther-
mal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber [ J ]. Polymer, 2008, 49( 1 ): 278 - 294.
[ 5 ] Francis B, Thomas S, Asari G V, et al. Synthesis of hydroxyl-ter-
minated poly (ether ether ketone) with pendent tert-butyl groups and its use as a toughener for epoxy resins [ J ]. Journal of Polymer Science Part B-Polymer Physics, 2006, 44( 3 ): 541 - 556.
[ 6 ] 周宏群. 环氧建筑结构胶的增韧改性研究[ D ]. 长沙:湖南大学土木工程学院,2011:33 - 47.
[ 7 ] Yun N G, Won Y G, Kim S C. Toughening of carbon fiber/epoxy composite by inserting polysulfone film to form morphology spectrum [ J ]. Polymer, 2004, 45( 20 ): 6 953 - 6 958.
[ 8 ] Luo H Y, Sun Z H, Zhao S Q. Fatigue crack propagation behavior of rubber toughened epoxy resin [ J ]. Tsinghua Science and Technology, 2000, 5( 1 ): 22 - 26.
[ 9 ] 李赫亮,刘敬福. KH-550对环氧胶粘涂层机械性能的影响 [ J ]. 表面技术,2002,31( 6 ):53 - 54.
[ 10 ] Callens M G, Gorbatikh L, Bertels E, et al. Tensile behaviour of s-
tainless steel fibre/epoxy composites with modified adhesion [ J ]. Composites Part A-Applied Science and Manufacturing, 2015( 69 ): 208 - 218.
[ 11 ] 赵 丹,吴 航,邵亚薇,等. KH-550改性环氧树脂与碳钢间的界面附着力研究[ J ]. 2010,23( 3 ):22 - 24.
[ 12 ] Wang X L, Lu M Y, Zhang T, et al. Facile fabrication and modific-
ation of epoxy acrylate latexes by epoxy resin and silane coupling agent [ J ]. Journal of Adhesion Science and Technology, 2015, 29( 2 ): 94 - 108.
[ 13 ] 崔 永,邢志国,吕振林,等. 偶联剂KH-550在改性环氧树脂胶粘SiC耐磨涂层中的应用[ J ]. 表面技术,2009,38( 1 ):20 - 22.
[ 14 ] Chen Y F, Yue W, Bian Z Z, et al. Preparation and properties of KH550-Al2O3/PI-EP nanocomposite material[ J ]. Iranian Poly-
mer Journal, 2013, 22( 5 ): 377 - 383.