1. Jiangsu SOPO Polyester Technology Corporation Ltd., Zhenjiang 212000, China; 2. Jiangsu University 212013, School of Chemistry and Chemical Engineering Zhenjiang , China; 3. Jiangsu Sopo Chemical Corporation Ltd.,
Zhenjiang 212006, China
Abstract:A series of chitosan-based boron nitride materials (BN-CSx, x=0, 20, 40) were prepared by using boric acid as the boron source and urea and chitosan as the double nitrogen sources by high-temperature calcination method. The structures of BN-CSx were analyzed by SEM, XRD, FT-IR and other characterization methods. Using dibenzothiophene (DBT) as the sulfide model, the adsorption performance of BN-CSx on DBT was compared and investigated. The results show that BN-CS20 had the best adsorption ability for DBT, and the adsorption capacity was up to 25.22 mg S/g. The results of kinetics, isotherm and thermodynamics experiments proved that the adsorption process of BN-CS20 on DBT coincided with the pseudo-second-order and Freundlich isotherm models, and room temperature was favorable to the adsorption.
[ 1 ] Al-Degs YS, El-Sheikh AH,Al Bakain, RZ, et al. Conventional a-
nd upcoming sulfur-cleaning technologies for petroleum fuel: A review[ J ]. Energy Technology 2016, 4( 6 ): 679 - 699.
[ 2 ] Rajendran A, Cui T-y,Fan, H-x, et al. A comprehensive review on oxidative desulfurization catalysts targeting clean energy and environment[ J ]. Journal of Materials Chemistry A 2020, 8( 5 ):2 246 - 2 285.
[ 3 ] Khan N A, Shin S, Jhung S H.Cu2O-incorporated MAF-6-deri-
ved highly porous carbons for the adsorptive denitrogenation of liquid fuel[ J ]. Chemical Engineering Journal 2020( 381 ): 122 - 675.
[ 4 ] Dong L, Dai X, Peng C, et al. Ultra-deep catalytic adsorptive des-
ulfurization of diesel fuel using Ti-silica gel adsorbent at low Ti-loading[ J ]. AICHE Journal 2022, 68( 2 ): 117 - 493.
[ 5 ] Zu Y, Guo Z, Zheng J, et al. Investigation of Cu(I)-Y zeolites with different Cu/Al ratios towards the ultra-deep adsorption desulfurization: Discrimination and role of the specific adsorption active sites[ J ]. Chemical Engineering Journal 2020( 380 ): 122 - 319.
[ 6 ] Kabtamu D M, Wu Y-n, Chen Q, et al. Facile upcycling of hazar-
dous Cr-containing electroplating sludge into value-added metal-organic frameworks for efficient adsorptive desulfurization[ J ]. ACS Sustainable Chemistry & Engineering 2020, 8( 33 ): 12 443 - 12 452.
[ 7 ] Watanabe S, Ma X, Song C. Adsorptive desulfurization of jet fuels over TiO2-CeO2 mixed oxides: Role of surface Ti and Ce cations[ J ]. Catalysis Today 2021( 371 ): 265 - 275.
[ 8 ] Balmain W H. Bemerkungen über die Bildung von Verbindungen des Bors und Siliciums mit Stickstoff und gewissen Metallen[ J ]. Journal für Praktische Chemie 1842, 27( 1 ): 422 - 430.
[ 9 ] Weng Q H, Wang X B, Zhi C Y, et al. Boron nitride porous micro-
beIts for hydrogen storage[ J ]. ACS Nano 2013, 7( 2 ): 1 558 - 1 565.
[ 10 ] Ma J H, Li J, Li G X, et al. One simple synthesis route to whisker-
like nanocrystalline boron nitride by the reaction of NaBH4 and NaN3[ J ]. Materials Research Bulletin 2007, 42( 5 ): 982 - 988.
[ 11 ] Marchesini S, McGilvery C M, Bailey J, et al. Template-free synt-
hesis of highly porous boron nitride: Insights into pore network design and impact on gas sorption[ J ]. ACS Nano 2017, 11 ( 10 ): 10 003 - 10 011.
[ 12 ] Yu M Y, Cui D L, Li K, et al. Hydrothermal synthesis of cubic b-
oron nitride crystals[ J ]. Acta Chimica Sinica 2005, 63( 10 ): 909 - 912.
[ 13 ] Boamah P O, Zhang Q, Hua M, et al. Lead removal onto cross-lin-
ked low molecular weight chitosan pyruvic acid derivatives[ J ]. Carbohydrate Polymers 2014( 110 ): 518 - 527.
[ 14 ] Chu K H. The kiselev isotherm for adsorption at the liquid-solid interface: solving the mystery of negative equilibrium constants[ J ]. Journal of Molecular Liquids 2021( 343 ): 5.
[ 15 ] Ganiyu S A, Ajumobi O O, Lateef S A. Boron-doped activated carbon as efficient and selective adsorbent for ultra-deep desulfurization of 4,6-dimethyldibenzothiophene[ J ]. Chemical Engineering Journal 2017( 321 ): 651 - 661.
[ 16 ] Chang Y H, Zhang L, Ying H J, et al. Desulfurization of gasoline using molecularly imprinted chitosan as selective adsorbents[ J ]. Applied Biochemistry Biotechnology 2010( 160 ): 593 - 603.
[ 17 ] Li H, Zhu S, Zhang M, et al. Tuning the chemical hardness of boron nitride nanosheets by doping carbon for enhanced adsorption capacity[ J ]. ACS Omega 2017, 2( 9 ): 5 385 - 5 394.
[ 18 ] Luo Z, Fang Y, Zhou M, et al. A Borocarbonitride ceramic aerogel for photoredox catalysis[ J ]. Angewandte Chemie-International Edition 2019, 58( 18 ): 6 033 - 6 037.
[ 19 ] Yu H, Chen Y F, Guo H Q, et al. Preparation of molecularly impr-
inted carbon microspheres by one-pot hydrothermal method and their adsorption properties to perfluorooctane sulfonate[ J ]. Chine-
se Journal of Analytical Chemistry 2019, 47( 11 ): 1 776 - 1 784.
[ 20 ] Li J, Xiao X, Xu X W, et al. Activated boron nitride as an effective adsorbent for metal ions and organic pollutants[ J ]. Scientific Reports 2013( 3 ): 7 - 9.
[ 21 ] Wang Z J, Yang X Y, Yang T J, et al. Dibenzothiophene dioxide based conjugated microporous polymers for visible-light-driven hydrogen production[ J ]. ACS Catalysis 2018, 8( 9 ): 85 - 90.
[ 22 ] Xiong J, Zhu W S, Li H P, et al. Few-layered graphene-like boron nitride induced a remarkable adsorption capacity for dibenzothio-
phene in fuels[ J ]. Green Chemistry 2015, 17( 3 ): 1 647 - 1 656.
[ 23 ] Foo K Y, Hameed B H. Insights into the modeling of adsorption isotherm systems[ J ]. Chemical Engineering Journal 2010, 156( 1 ): 2 - 10.