新型金属有机凝胶及其复合物的制备

doi:10.19286/j.cnki.cci.2023.02.035

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摘要金属-有机凝胶（Metal-organic gels MOG）通常是用有机溶液制备的，因其独特的性质引起了人们的广泛关注。近年来，金属有机凝胶作为一类新型多孔材料的出现，由于其较大的比表面积、高孔隙率、丰富的孔道结构和功能基团等特点，在水处理、医疗、储存、环境修复和催化等方面具有潜在的应用前景。MOG材料是制备其他复合金属有机凝胶的前提，与其他复合材料相比，MOG具有优异的性能，因此合成了一种新型的金属有机凝胶(MOGS)。本综述旨在简要介绍金属有机凝胶及其复合物Zr-MOG、Al-MOG、Fe-MOG的最常用制造方法。从可持续发展的角度出发，为吸附水中污染物的有效利用提供了一条可持续发展的途径。最后，还总结了MOG及其复合物开发相关的挑战、未来趋势和前景。

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	王宇
	林英姿

关键词 ：金属有机凝胶, Zr-MOG, Al-MOG, Fe-MOG, 制备方法, 可持续发展

Abstract：Metal-organic gels (MOGs) are usually prepared from organic solutions and have attracted a lot of attention because of their unique properties. In recent years, metal organogels have emerged as a new class of porous materials with potential applications in water treatment, medical treatment, storage, environmental remediation and catalysis due to their large specific surface area, high porosity, rich pore structure and functional groups. MOG materials are a prerequisite for the preparation of other composite metal organogels, and a new type of metal organogel (MOGS) was synthesized because of the excellent properties of MOG compared with other composites. The purpose of this review is to briefly introduce the most commonly used methods for the fabrication of metal organogels and their complexes Zr-MOG, Al-MOG, and Fe-MOG. It provides a sustainable pathway for the effective use of pollutants in adsorbed water from the perspective of sustainable development. Finally, the challenges, future trends and prospects related to the development of MOG and its complexes are also summarized.

Key words： Metal-organic gels MOG Zr - MOG Al - MOG Fe - MOG preparation method sustainable development

基金资助:国家自然科学基金《饮用水净化工艺全流程中的卤乙腈分布特征及其前体物研究》（51778267）；国家水体污染控制与治理科技重大专项《老旧城区供水管网水质保障及改扩建技术研究》（2012ZX074088001）；吉林省科技厅《北方城市饮用水安全保障技术研究》（20220203047SF）

作者简介: 王宇（ 1998— ），女，吉林延边人，硕士研究生。

引用本文:

王宇，林英姿. 新型金属有机凝胶及其复合物的制备[J]. 煤炭与化工, 2023, 46(2): 127-129，137.. Wang Yu, Lin Yingzi. Preparation of novel organometallic gels and their compounds. CCI, 2023, 46(2): 127-129，137..

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http://www.mtyhg.com.cn/CN/10.19286/j.cnki.cci.2023.02.035 或 http://www.mtyhg.com.cn/CN/Y2023/V46/I2/127

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