苯选择性加氢制环己烯催化技术研究进展

doi:10.19286/j.cnki.cci.2018.08.043

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Abstract

The catalyst of selective hydrogenation of benzene to cyclohexene was summarized,and It the series of benzene selective hydrogenation catalyst developed by Zhengzhou University were focused on.It is suggested because the technical route of benzene selective hydrogenation catalytic technology is environmentally friendly and because the resource-efficient. China has become the second country in the world to achieve industrialization and own independent intellectual property rights. However, there are some problems in the production and application of this catalyst, such as loss and difficulty in regulation,so in the future, more mature benzene selective hydrogenation technology should be developed, and catalysts with better simple performance should be prepared.

Key words： benzene selective hydrogenation cyclohexene Ru catalyst

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	Kang Lina

Cite this article:

Kang Lina. Research progress on catalysts for selective hydrogenation of benzene to cyclohexene[J]. CCI, 2018, 41(8): 130-132.

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http://www.mtyhg.com.cn/EN/10.19286/j.cnki.cci.2018.08.043 OR http://www.mtyhg.com.cn/EN/Y2018/V41/I8/130

1 ]       赵立芳，郭进宝. 环己烯合成方法研究[ J ]. 精细石油化工进展，2004，5（ 7 ）：19 - 23.
[ 2 ]       Drinkard W C. Catalysts and catalysts system for selective partial hydrogenation: DE, 2221137A[ P ]. 1972.
[ 3 ]       Drinkard W C. A heterogeneous system for selective partial hydro-
genation: NL, 7205832[ P ]. 1972.
[ 4 ]       贾继飞，张    涛，徐竹生，等. 苯选择加氢制环己烯的研究进展[ J ]. 精细石油化工，1997（ 3 ）：46 - 50.
[ 5 ]       Horiuti I, Polanyi M. The Mechanism of Benzene Hydrogenation Trans[ J ]. Faraday Soc, 1934, 30：1 164 - 1 172.
[ 6 ]       R Truffault. Catalytic hydrogenation of aromatic hydrocarbons in liquid media in the presence of nickel black and phosphoric anhydride[ J ]. Bull Soc Chem, 1934，5（ 1 ）：391 - 406.
[ 7 ]       Anderson J R. The Catalytic Hydrogenation of Benzene and Toluene over Evaporated Films of Nickel and Tungsten[ J ]. Aust J Chem, 1957, 10：409 - 416.
[ 8 ]       Hartog F, Zwietering P. Olefins as Intermediates in the hydrogena-
tion of Aromatic Hydrocarbons[ J ]. J Catal, 1963, 2：79 - 81.
[ 9 ]       Johnson M M, Nowack G P. Selective hydrogenation of aromatics:US, 3793383[ P ]. 1974.
[ 10 ]     Nowack G P, Johnson M M. Hydrogenation catalysts: US, 4401640[ P ]. 1975.
[ 11 ]     Niwa S I, Mizukami F, Isoyama S, et al. Selective Hydrogenation of Benzene to Cyclohexene with ruthenium Catalysts prepared by a chemical Mixing Procedure[ J ]. Preparation and Properties of the Catalysts J Mol Catal, 1986, 34：247 - 249.
[ 12 ]     Mallat T, Baiker A. Selectivity Enhancement in Heterogeneous Catalysis Induced by Reaction Modifiers[ J ]. Appl Catal A：Gen，
              2000，200：3 - 22.
[ 13 ]     Mazzieri V, Figolia N, Pascualb F C, et al. Effect of the Support on the Selective Hydrogenation of Benzene over Ruthenium Catalysts. I.Al2O3 and SiO2 [ J ]. Catal lett, 2005, 102：1 - 2.
[ 14 ]     Da-Costa P Z, Landers R, Cobo A J G.Thermal Treatment Effects on the Ru/CeO2 Catalysts Performance for Partial Hydrogenation of Benzene[ J ]. Appl Surf Sci, 2008，254：6 849 - 6 853.
[ 15 ]     王海荣. 苯选择加氢制环己烯新型Ru催化剂的研究[ D ]. 郑州大学，2001.
[ 16 ]     王栋斌. Zn含量对Ru-Zn催化剂性能和寿命的影响[ D ]. 郑州大学，2010.
[ 17 ]     孙海杰. [ Zn（OH）2]3 （ZnSO4）（H2O）x 修饰的Ru催化剂上苯选择加氢制环己烯[ D ]. 郑州大学，2013.
[ 18 ]     张元馨. 苯选择加氢催化剂活性选择性调变方法和调变机理[ D ]. 郑州大学，2015.
[ 19 ]     孙海杰，郭    伟，周小莉，陈志浩，刘仲毅，刘寿长. 非晶态合金Ru基催化剂在苯选择加氢中的应用进展[ J ]. 催化学报，2011（ 1 ）：33 - 36.
[ 20 ]     袁吴魏，姚志龙. 苯选择性加氢制备环己烯技术进展[ J ]. 化工进展，2010（ S2 ）：105 - 107.
[ 21 ]     张向京，郭欣欣，赵    莹，等. 微乳体系中苯部分加氢制备环己烯[ J ]. 河北科技大学学报，2010（ 1 ）：25 - 28.
[ 22 ]     黄振旭，刘寿长. 苯加氢制环己烯Ru-Zn/ZrO2催化剂的制备和表征[ J ]. 河南化工，2009（ 6 ）：56 - 58.
[ 23 ]     龙    帅，张爱清，刘汉范. 铂纳米簇/聚酰亚胺杂化膜反应器的制备及其在催化苯部分加氢中的应用[ N ]. 催化学报，2009 - 4.
[ 24 ]     宋    颖，金长青，薛    伟，等. Ru-Zn@SiO2催化苯选择加氢制环己烯研究[ N ]. 河北工业大学学报，2009 - 1.
[ 25 ]     余加祐，王明章，张秀玲，等. 固载化离子液体在催化加氢反应中的研究进展[ N ]. 大连工业大学学报，2008 - 2.
[ 26 ]     秦会安，黄振旭，刘寿长. 苯选择加氢制环己烯无负载Ru-Zn-B催化剂的研究[ J ]. 信阳师范学院学报（自然科学版），2007（ 3 ）：23 - 25.
[ 27 ]     魏作君，黄    勇，刘迎新. 离子液体在非均相催化反应中的应用研究进展[ J ]. 现代化工，2007（ 5 ）：36.
[ 28 ]     Shouchang Liu, Zhongyi Liu, Shuhui Zhao.Study on the Nanosized Amorphous Ru-Fe-B/ZrO2 Alloy Catalyst for Benzene Selective Hydrogenation to Cyclohexene[ J ]. Journal of Natural Gas Chemi-
stry，2006（ 4 ）：45 - 47.