光耦合金属基催化剂活化过硫酸盐降解有机污染物的进展研究

doi:10.19286/j.cnki.cci.2025.04.029

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摘要

在众多水处理技术中，过硫酸盐高级氧化法（AOPs）因其产生高活性的硫酸根自由基（SO4·-）以及羟基自由基（·OH），具有高效的矿化能力，受到越来越多的关注。开发了一种安全、经济、环保的过硫酸盐高级氧化法处理有机污染物的活化技术。光催化是一种绿色、环保的过硫酸盐活化方法，过硫酸盐体系中的光催化剂可以提高光的利用率，将过硫酸盐转化为活性物种降解有机污染物。首先从作用机理介绍了不同过硫酸盐在反应体系中的选取，讨论了金属基光催化剂的活化，介绍了在实际应用中面临的挑战，并结合目前研究现状对未来发展方向进行展望，为过硫酸盐活化技术在处理污染物应用上提供一定的参考。

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	李强
	赵玉鑫
	蒋宝军

关键词 ：过硫酸盐高级氧化法, 光活化, 金属基催化剂

Abstract：

Among many water treatment technologies, advanced oxidation of persulfates (AOPs) has received increasing attention due to its efficient mineralisation ability by generating highly reactive sulfate radicals (SO4·-) as well as hydroxyl radicals (-OH). A safe, economical, and environmentally friendly activation technology for the treatment of organic pollutants was developt by advanced oxidation of persulfate. Photocatalysis is a green and environmentally friendly method of persulfate activation, and the photocatalyst in the persulfate system can improve improve the utilisation of light and convert persulfate into active species to degrade organic pollutants. The selection of different persulfates in the reaction system from the mechanism of action were introduced, then the activation of metal-based photocatalysts were discussed, and the challenges faced in practical applications were introduced, and the future direction of development in the light of the current state of research was looked forward, and the certain reference for the application of persulfate activation technology in the treatment of pollutants were provided.

Key words： advanced persulfate oxidation photoactivation metal-based catalysts

基金资助:

吉林省住房与城乡建设厅（2023-K-17）

通讯作者: 赵玉鑫（ 1975— ），女，吉林长春人，教授。

作者简介: 李强（ 1995— ），男，山西忻州人，在校生。

引用本文:

李强，赵玉鑫,蒋宝军. 光耦合金属基催化剂活化过硫酸盐降解有机污染物的进展研究[J]. 煤炭与化工, 2025, 48(4): 138-142. Li Qiang， Zhao Yuxin， Jiang Baojun. Progress study on degradation of organic pollutants by activation of persulfate over photocoupled metal-based catalysts. CCI, 2025, 48(4): 138-142.

链接本文:

http://www.mtyhg.com.cn/CN/10.19286/j.cnki.cci.2025.04.029 或 http://www.mtyhg.com.cn/CN/Y2025/V48/I4/138

[ 1 ]       白    静. 非均相催化过硫酸盐氧化技术研究进展[ J ]. 化工环保，2019，39（ 3 ）：247 - 254.
[ 2 ]       刘楚汉. 过硫酸盐活化技术研究进展及展望[ J ]. 伊犁师范学院学报（自然科学版），2020，14（ 2 ）：48 - 54.
[ 3 ]       Wang C. Water Purification: Metal-Organic Frameworks and Their Derived Materials: Emerging Catalysts for a Sulfate Radicals-Bas-
ed Advanced Oxidation Process in Water Purification[ J ]. Small, 2019( 16 ): 15 - 17.
[ 4 ]       Xiao S.Iron-mediated activation of persulfate and peroxymonosul-
fate in both homogeneous and heterogeneous ways[ J ]. A review, 2019( 384 ): 123 - 142.
[ 5 ]       Lee J, U von Gunten, J-H Kim. Persulfate-Based Advanced Oxi-
dation: Critical Assessment of Opportunities and Roadblocks[ J ]. Environmental Science & Technology, 2020, 54( 6 ): 3 064 - 3 081.
[ 6 ]       Wacawek S. Chemistry of persulfates in water and wastewater tre-
atment[ J ]. A review, 2017, 330( 15 ): 44 - 62.
[ 7 ]       Huang W. Activation of persulfate by carbonaceous materials[ J ]. A review, 2021( 3 ): 129 - 137.
[ 8 ]       Xiao P F, L An, D D J N C M Wu. The use of carbon materials in persulfate-based advanced oxidation processes[ J ]. A review, 2020, 35( 6 ): 667 - 683.
[ 9 ]       Song W.A mini review of activated methods to persulfate-based a-
dvanced oxidation process[ J ]. A review, 2019, 79( 3 ): 573 - 579.
[ 10 ]     余烨颖. 可见光活化过一硫酸盐降解有机污染物的研究进展[ J ]. 杭州师范大学学报（自然科学版）2021，20（ 6 ）：48 - 54.
[ 11 ]     Yan W. Deciphering co-catalytic mechanisms of potassium doped g-C3N4 in Fenton process[ J ]. A review, 2020, 392( 33 ): 122 - 136.
[ 12 ]     He S. Consolidated 3D Co3Mn-layered double hydroxide aerogel for photo-assisted peroxymonosulfate activation in metronidazole degradation[ J ]. A review, 2021( 423 ): 130 - 142.
[ 13 ]     Ghanbari F, M.J.C.E.J.Moradi.Application of peroxymonosulfate-
and its activation methods for degradation of environmental organic pollutants[ J ]. Review, 2016（ 310 ）: 307 - 315.
[ 14 ]     B Y.Z.A.Comparison of amoxicillin photodegradation in the UV/
H2O2 and UV/persulfate systems: Reaction kinetics, degradation pathways, and antibacterial activity[ J ]. A review, 2019( 372 ): 420 - 428.
[ 15 ]     Battula V R, A. Jaryal,K.J.J.o.M.C.A. Kailasam, Visible light-dri-
ven simultaneous H2 production by water splitting coupled with selective oxidation of HMF to DFF catalyzed by porous carbon nitride[ J ]. A review, 2019( 278 ): 320 - 328.
[ 16 ]     A J.Y., M.Z.A, D.D.D.J.W.R. B. What is the role of light in persu-
lfate-based advanced oxidation for water treatment[ J ]. A review, 2020( 259 ): 189 - 213.
[ 17 ]     Yang Q. Recent advances in photo-activated sulfate radical-adv-
anced oxidation process (SR-AOP) for refractory organic pollutants removal in water[ J ]. A review, 2019( 378 ): 122 - 149.
[ 18 ]     Kim C. Activation of Persulfate by Nanosized Zero-Valent Iron (N
ZVI): Mechanisms and Transformation Products of NZVI[ J ]. A review,2018, 52( 6 ): 3 625 - 3 633.
[ 19 ]     A R.S., et al., The ZVI-Fenton process affects the total load of hu-
man pathogenic bacteria in wastewater samples - ScienceDirect[ J ]. A review, 2022( 226 ): 220 - 223.
[ 20 ]     Jiang B. Experimental study on the treatment of landfill leachate by electro-assisted ZVI/UV synergistic activated persulfate system[ J ]. A review, 2022, 12( 7 ): 768 - 783.
[ 21 ]     Meng F. Enhanced degradation of Rhodamine B via α-Fe2O3 mi-
crospheres induced persulfate to generate reactive oxidizing species[ J ]. Environmental Science & Technology, 2020( 243 ): 125 - 133.
[ 22 ]     Yu, X., et al., Integration of SO4-based AOP mediated by reusable iron particles and a sulfidogenic process to degrade and detoxify Orange II[ J ]. Environmental Science & Technology, 2020( 174 ): 115 - 122.
[ 23 ]     Zheng X. Metal-based catalysts for persulfate and peroxymonosul-
fate activati on in heterogeneous ways[ J ]. A review, 2022( 429 ): 132 - 145.
[ 24 ]     B Y.S.A.Efficient removal of trichloroethene in oxidative environ-
ment by anchoring nano FeS on reduced graphene oxide supported nZVI catalyst: The role of FeS on oxidant decomposition and iron leakage[ J ]. Environmental Science & Technology, 2020( 392 ): 122 - 129.
[ 25 ]     Cai J., Y.J.E.S, Zhang P. Research, Enhanced degradation of bisp-
henol S by persulfate activated with sulfide-modified nanoscale zero-valent iron[ J ]. Environmental Science & Technology, 2021( 210 ): 138 - 152.
[ 26 ]     Liu. Visible-light-driven photocatalytic activation of peroxymono-
sulfate by Cu-2(OH)PO4 for effective decontamination[ J ]. Environmental Science & Technology, 2018( 14 ): 220 - 237.
[ 27 ]     胡嘉敏. 紫外强化铜循环催化过硫酸盐降解甲基橙[ J ]. 杭州师范大学学报, 2021( 18 ): 123 - 129.