|
|
|
| Synthesis and Properties of Polyoxyethylene ether sulfonate Surfactants |
| KANG Ying-xin1, WANG Xue-liang2, ZHANG Li-hong1, ZHAO Di-shun2 |
| 1. Hebei Nalixin Wash and Chemical Corporation Ltd.,Shenze 052560, China; 2. College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology, Shijiazhuang 050018, China |
|
|
|
|
Abstract Polyoxyethylene ether sulfonate surfactants are a novel type of surfactants, of which a polyoxyethylene chain is embedded between hydrophilic ionic and hydrophobic group tail to meet the needs of tertiary oil recovery. According to the domestic and foreign related literatures, the surface activity properties, foam properties, emulsifying properties, antiscaling performance, thermal stability and salt resistance, and the application prospect of this kind of surfactants in the exploitation of crude oil were discussed. It was pointed that further development of the polyoxyethylene ether sulfonate surfactants should focus on the following aspects which were designing and developing the green synthesis routes of polyoxyethylene ether sulfonate surfactant, strengthening the performance of the hydrophobic groups type and the EO number of the surfactants, seeking for better comprehensive performance surfactants, synergizing the polyoxyethylene ether sulfonate surfactants with other surfactants to expand the application in tertiary oil recovery and other fields.
|
|
|
|
|
|
| [ 1 ] Zhang F, Hao J K, Lv W, et al. Design and application of down hole oil production and water injection separation in the same well of high water cut and fault block oilfield [ J ]. Fault-Block Oil & Gas Field,2010, 17( 3): 357 - 359.[ 2 ] 方 云. 表面活性剂合成中的磺乙基化反应[ J ]. 日用化学工业, 1992( 3 ):23-28.[ 3 ] MCCOY D R. Process for making ether sulfonates[ P ]. US: 4226807, 1980-10-07.[ 4 ] 汪学良,赵地顺,崔 云,等. 椰油醇聚氧乙烯醚磺酸钠的合成及表面活性[ J ]. 日用化学工业,2013,43( 2 ):100 - 104.[ 5 ] 王业飞, 黄建滨. 氧乙烯化十二醇醚丙撑磺酸钠合成及表面活性[ J ]. 物理化学学报,2001,17( 6 ):488 - 490.[ 6 ] Wuest W, Eskuchen R, Richter B. Process for the production of surfactant mixtures based on ether sulfonates andtheiruse[ P ]. US: 5318709, 1994-06-07.[ 7 ] 王业飞,赵福麟. 由AES合成脂肪醇聚氧乙烯醚磺酸钠的研究[ J ]. 精细石油化工,1996( 5 ):22 - 24 .[ 8 ] 杨 铭,郭 奕,陈 楠,等. 脂肪醇醚硫酸盐直接转化合成醇醚磺酸盐[ J ]. 日用化学工业, 2011, 41( 2 ):79 - 82.[ 9 ] 贺伟东,李瑞冬,葛际江,等. 辛基酚聚氧乙烯醚磺酸盐的合成与界面张力的测定[ J ]. 石油化工高等学校学报, 2010,23( 4 ):20-24.[ 10 ] 牛金平,韩亚明. 驱油用磺酸盐的工业化生产现状与发展趋势[ J ]. 日用化学品科学,2008,31( 11 ):4 - 7.[ 11 ] Minero C, Pramauro E, Pelizzettle, et al. Micellar properties of sodium dodecylpoly( oxyethylene) sulfates[ J ]. J Phys Chem, 1986, 90:1 620 - 1 625.[ 12 ] 曹翔宇,龙海华,崔正刚. 醇醚磺酸盐的合成及其耐温耐盐和界面化学性能研究[ J ]. 日用化学工业,2011,41( 2 ):92 - 96.[ 13 ] 张锁兵,程 月,田春友,等. 脂肪醇聚氧乙烯醚系列磺酸盐的泡沫性能研究[ J ]. 日用化学工业,2007,37( 3 ): 172 - 175.[ 14 ] 王显光,王 琳,任立伟,等. 新型阴-非离子型表面活性剂的泡沫性能[ J ]. 油田化学,2009,26( 4 ):357 - 361.[ 15 ] 张永民,牛金平,李秋小. 脂肪醇聚氧乙烯醚磺酸钠的性能研究[ J ]. 化学研究与应用,2009,21( 7 ): 964 - 968.[ 16 ] 张继超,马宝东,张永民,等. 不同氧乙基数十六烷基聚氧乙烯醚磺酸钠的界面性能[ J ]. 日用化学工业,2011,41(2 ):87 - 91.[ 17 ] 葛际江,张贵才,李德胜. OPS和OPC系列稠油乳化降粘剂的研制[ J ]. 油田化学,2007,24( 1 ):30 - 33.[ 18 ] 李立勇,周 忠,崔正刚,等. 脂肪醇聚氧乙烯醚磺酸盐耐温耐盐性研究[ J ]. 精细石油化工进展,2008,9( 7 ):4-5.[ 19 ] 任朝华,罗 跃,陈大钧. 辛基酚聚氧乙烯醚烷基磺酸钠溶液的性能研究[ J ]. 应用化工,2010,39( 9 ):1 338 - 1 340.[ 20 ] 杨晓鹏,郭东红,辛浩川,等. 脂肪醇聚氧乙烯醚磺酸盐NNA系列高温高盐条件下界面活性研究[ J ]. 油田化学, 2009,26( 4 ):423 - 424.[ 21 ] 贺伟东,葛际江,张贵才,等. 烷基醇/酚聚氧乙烯醚磺酸盐的性能与应用前景[ J ]. 日用化学工业,2011,41( 2 ):122 - 126.[ 22 ] 贺伟东,蒋燕军,靳路超,等. 不同结构聚醚磺酸盐的耐盐性能和起泡性能研究[ J ]. 石油与天然气化工,2011,40(5 ):475 - 479.[ 23 ] 徐 军,孙文起,李干佐. DSB显著提高羧酸盐驱油体系抗钙镁离子能力的研究[ J ]. 高等学校化学学报,2007,28(3 ):496 - 501. |
|
|
|