苯部分加氢催化剂制备及性能评价

doi:10.19286/j.cnki.cci.2025.10.027

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Abstract

A catalyst for partial hydrogenation of benzene and its preparation method were developed. Based on the active components of the traditional Ru-Zn catalyst, a trace amount of Pd metal was added to the catalyst, and the preparation technology of the catalyst was optimized. The results show that the preparation technology of the catalyst makes the components of the catalyst more dispersed and uniform. The reaction activity and stability of the catalyst were further improved, and its conversion rate and selectivity reached more than 40%, 84%, 45% and 80% respectively, which effectively reduced the catalyst unit consumption in production. At the same time, the sensitivity (antitoxicity) to sulfur was also obviously improved, which is characterized by high reaction index and stability. The performance indexes such as catalyst activity and sulfur resistance have reached the leading level in China. The application of catalysts with high activity and stability can significantly reduce production energy consumption, improve the core technology competitiveness of enterprises, and produce favorable economic and social benefits.

Key words： partial hydrogenation of benzene catalyst reactive activity conversion rate selectivity antitoxicity

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	Yin Lijing

Cite this article:

Yin Lijing. Preparation and performance evaluation of catalyst for partial hydrogenation of benzene[J]. CCI, 2025, 48(10): 134-137.

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http://www.mtyhg.com.cn/EN/10.19286/j.cnki.cci.2025.10.027 OR http://www.mtyhg.com.cn/EN/Y2025/V48/I10/134

[ 1 ]       王红琴，谢继阳，安霓虹，等. 钌基催化剂催化苯部分加氢制环己烯的研究进展[ J ]. 材料导报，2019，33（ 12 ）：4 016 - 4 024.
[ 2 ]       肖进贤，孙    斌，宗保宁. 苯选择加氢制环己烯负载型催化剂研究进展[ J ]. 石油学报（石油加工），2014，30（ 5 ）：934 - 944.
[ 3 ]       武汉优力克新材料科技有限公司. 尹华清，蒋遥明; 罗光辉.一种苯部分加氢制环己烯催化剂及生产环己烯的方法：中国，CN103191732A[ P ]. 2013 - 07 - 10.
[ 4 ]       宋红光. 苯部分加氢催化剂劣化原因及工艺参数计算[ J ]. 广州化工，2018，46（ 1 ）：159 - 160.
[ 5 ]       周功兵，王    浩，裴    燕，等. Ru-Zn/ZrO2催化剂在苯部分加氢反应中的孔径效应[ J ]. 化学学报，2017（ 75 ）：321 - 328.
[ 6 ]       周功兵，刘建良，田    静，等. Pd、Pt对 Ru/ZrO2催化剂苯部分加氢性能的修饰作用[ J ]. 中国科学：化学，2018，48（ 5 ）：535 - 544.
[ 7 ]       徐    杰，宁剑波，刘    菁. 用于苯催化选择性加氢反应的催化剂及制备方法和应用：中国，CN101195090A[ P ]. 2008 - 06 - 11.
[ 8 ]       王树东，赵玉军，周    瑾. 用于苯加氢反应的催化剂及制备方法和应用：中国，CN1795983A[ P ]. 2008 - 09 - 24.
[ 9 ]       刘寿长. 苯加氢生成环己烯工艺、所用催化剂及其制备方
              法：中国， CN1696086A[ P ]. 2005 - 11 - 16.
[ 10 ]     刘寿长，李利民. 苯选择性加氢制环己烯催化剂及其制
              造方法：中国，CN1597099A[ P ]. 2005 - 03 - 23.
[ 11 ]     张结实. 苯部分加氢制环己烯催化剂性能研究[ D ]. 北京：北京化工大学，2014：25 - 27.
[ 12 ]     杨国杰. 苯部分加氢制环己烯工艺优化研究[ D ]. 北京：北京化工大学，2017：30 - 33.
[ 13 ]     安红强，王运涛，杨国杰，等. 高活性高选择性苯部分加氢制环己烯催化剂的探究[ J ]. 化工管理，2023（ 7 ）：144 - 146.
[ 14 ]     喻雪莲. Ru@XO2(X=Ti,Zr和Si)催化剂应用于苯部分加氢制环己烯[ D ]. 上海：华东理工大学，2018：22 - 24.
[ 15 ]     董    森，刘树俊，郭学华. 合成方法对 Ru-Zn/ZrO2 苯部分加氢催化剂的影响[ J ]. 工业催化，2021，29（ 4 ）：64 - 67.
[ 16 ]     沈亚峰，安霓虹，张孟旭，等. Ru-Zn/ZrO2 催化剂的制备及其苯选择性加氢性能研究[ J ]. 贵金属，2017，38（ 1 ）：6 - 10.
[ 17 ]     刘有鹏，孙国芳，高    鹏，等. 苯部分加氢制环己烯钌基催化剂研究进展[ J ]. 工业催化. 2015，23（ 4 ）：266 - 271.
[ 18 ]     Sun H J, Pan Y J, Li S H, et al. Selective hydrogenation of benzene to cycohexene over Ce-promoted Ru catalysts[ J ]. 能源化学（英文版），2013，22（ 5 ）：710 - 716.
[ 19 ]     Sun H J, Jiang H B, Wang H X, et al. Selective hydrogenation of benzene to cyclohexene over nanocomposite Ru-Mn/ZrO2 catslysts[ J ]. Chinese Journal of Catalysis，2013，34( 4 ): 684 - 694.
[ 20 ]     Yuan P Q, Ma Y M, Li X K, et al. Hydrophilic property of Ru(0 0 0 1) with and without H adatoms[ J ]. Journal of Molecular Structure Theochem, 2010，972( 1 ): 77 - 82.
[ 21 ]     Zhao Y J, Zhou J, Zhang J G, et al. Liquid-phase selective hydro-
genation of benzene to cyclohexene on Ru/Al2O3-ZrO2/cordierite monolithic catalysts[ J ]. Journal of Molecular Catalysis A，2009，
309(1 - 2): 35 - 39.