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| Study of factors affecting contact absorption of CO2 by PTFE membrane |
| Guo Aihong, Yao Jiming |
| North China University of Science and Technology College of Chemical Engineering, Tangshan 063210, China |
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Abstract In order to reduce carbon dioxide emissions from shipping, seawater was selected as the absorber, and the decarbonization rate was used as the evaluation index to investigate the effects of seawater temperature, seawater flow rate, CO2 gas mixture flow rate, CO2 concentration,and seawater pH value on the absorption of CO2. The results showed that seawater temperature and pH value affected the solubility and neutralization reaction of CO2, with the highest decarbonization rates respectively of 64.83% and 87.67% at the temperature of 18 ℃ and pH=8. The concentration of CO2 affects the difference in CO2 concentration between the gas and liquid phases,and the highest decarbonization rate(67.81%) at 20%, Seawater flow rate affected the renewal rate of the absorbent at the gas-liquid contact surface,and the best decarbonization rate is 200 L/h. CO2 gas mixture flow rate affected the residence time of the mixture in the membrane contact reactor, and the decarbonization rate was the best at 0.10 m3/h optimized conditions for contact absorption of CO2 by PTFE membranes.
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| [ 1 ] 李璐蕊,叶 舣,密建国,等. 膜吸收CO2捕集技术的研究[ J ]. 现代化工,2023,43( 11 ):15 - 19.
[ 2 ] 孙 烨,王兴旺,楚海强,等. 二氧化碳脱除技术研究综述[ J ]. 辽宁化工,2023,52( 6 ):884 - 887.
[ 3 ] 李福昭,毕金鹏,吕月霞,等. 中空纤维膜接触器捕集燃煤电厂烟气中CO2研究进展[ J ]. 齐鲁工业大学学报,2023,37( 4 ):14 - 24.
[ 4 ] Stewart P B, Munjal P K. Solubility of carbon dioxide in pure wat-
er, synthetic seawater, and synthetic sea water concentrates at-5.deg.to 25.deg.and 10-to 45-atm.Pressure[ J ]. Journal of Chemical &. Engineering Data, 1970, 15( 1 ): 67 - 71.
[ 5 ] Weiss R F. Carbon dioxide in water and seawater: the solubility of a non-ideal gas[ J ]. Marine Chemistry, 1974, 2( 3 ): 203 - 215.
[ 6 ] 张长金,尹燕华,龚峻松,等. 中空纤维膜接触器吸收低浓度CO2气体研究[ J ]. 舰船科学技术,2010,32( 12 ):55 - 59.
[ 7 ] 朱宝库,陈 炜,王建黎,等. 膜接触器分离混合气中二氧化碳的研究[ J ]. 环境科学,2003( 5 ):34 - 38.
[ 8 ] M.Ajdar, A.Azdarpour, A.Mansourizadeh, et al.Improvement of p-
orous polyvinylidene fluoride-co-hexafluropropylene hollow fiber membranes for sweeping gas membrane distillation of ethylene glycol solution[ J ]. Chinese Journal of Chemical Engineering, 2020, 28( 12 ): 3 002 - 3 010.
[ 9 ] 孙承贵. 中空纤维致密膜基吸收脱除CO2研究[ D ]. 大连:中国科学院研究生院(大连化学物理研究所),2005. |
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