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| Study on the temporal and spatial variation of VOCs in environmental air of Shijiazhuang City |
| Wang Mengxuan, Tian Jianli, Song Lan, Cui Jiansheng, Liu Daxi, Duan Lili |
| Insititute of Environmental Science and Engineeringm, Hebei University of Science and Technology, Shijiazhuang 050081, China |
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Abstract At present, the environmental air situation in our country is very severe, and the kinds of pollutants in the atmosphere are various and complex. The main pollutant that leads to the deterioration of the atmospheric environment quality is volatile organic pollutant (VOCs) that exists widely in the air, which composition is complex and is easy to react with other components in ambient air to form secondary organic aerosol which is harmful to the environment and human health. Avolume of 3 L Suma cans (SUMMA) was used for sample collection. The QP 2010 Plus gas chromatography/mass spectrometer was used for qualitative and quantitative analysis of VOCs in Shijiazhuang urban area. It is found that the total mass concentration of VOCs in the ambient air of Shijiazhuang is 15.33 ~ 145.07 μg/m3, the average concentration is 40.36 μg/m3; the concentration of dichloromethane accounts for the largest total concentration of VOCs, up to 13.70%, follows by toluene accounted for 12.63%; the characteristic pollutants are difluoromethylene chloride, methyl chloride, dichloromethane, 1,2-dichloroethane, benzene, toluene; New and High-tech Zones VOCs concentration is generally high; VOCs and PM2.5 show the best correlation, 0.82.
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| [ 1 ] 邵 敏,董 东. 我国大气挥发性有机物污染与控制[ J ]. 环境保护,2013( 5 ):25 - 28.
[ 2 ] Varutbangkul V, Brechtel F, BahreiniR, et al. HygroscoPicity of secondary organic Aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterepenes, and related compounds[ J ].Atmo-
spheric Chemistry and Physics, 2006, 6: 2 367 - 2 388.
[ 3 ] Derwent R G, Jenkin M E, Saunders S M, et al. Photochemical ozone formation in noeth west Europeand its control [ J ]. Atmos-
pheric Environment, 2003( 14 ): 1 983 - 1 991.
[ 4 ] 韩 萌,卢学强,冉 靓,等. 天津市城区夏季VOCs来源解析[ J ]. 环境科学与技术,2011,34( 10 ):76 - 80.
[ 5 ] Guenther A, Hewitt C N.A global-model of volatile-compound emission[ J ]. Joumal of Geophysical Research-Atmospheres, 1995, 100 ( 5 ): 8 873 - 8 892.
[ 6 ] 汤大纲,鲍林发,谢邵东,等.中国大气挥发性有机物和氨派昂研究[ R ]. 中国环境科学研究院,2005.
[ 7 ] 罗达通,高 健,高淑兰,等. 北京秋季大气挥发性有机物及相关污染物特征分析[ J ]. 中国科学院大学学报,2014,31( 3 ):329 - 336.
[ 8 ] 张俊刚,王跃思,王 珊,等. 京津地区大气中非甲烷烃(NMHCs)质量水平和反应活性研究[ J ]. 环境科学研究,2008,21( 5 ):158 - 162.
[ 9 ] Wang M, Shao M, Lu S H, et al. Evidence of coal contribution to ambient VOCs during in Beijing[ J ]. Chinese Chemical Letters, 2013, 24( 9 ): 829 - 832.
[ 10 ] 朱少峰,黄晓峰,何凌燕,等. 深圳大气VOCs浓度的变化特征与化学反应活性[ J ]. 中国环境科学,2012,32( 12 ):2 140 - 2 148.
[ 11 ] 邓雪娇,周秀骥,吴 兑,等. 珠江三角洲大气气溶胶对地面臭氧变化的影响[ J ]. 中国科学:地球科学,2011,41( 1 )93 - 102.
[ 12 ] 李 雷,李 红,王学中,等. 广州市中心城区环境空气中挥发性有机物的污染特征与健康风险评价[ J ]. 环境科学,2013,34( 12 ):4 558 - 4 564.
[ 13 ] 郑伟巍,毕晓辉,吴建会,等. 宁波市大气挥发性有机物污染特征及关键活性组分[ J ]. 环境科学研究,2014,27( 12 ):1 411 - 1419.
[ 14 ] Cal C, Geng F, Tie X, et al. Source apportionment of VOCs in the northerm suburb of Nanjing in Summer[ J ]. Environmental Science, 2013, 34( 12 ): 4 519 - 4 528.
[ 15 ] 苏雷燕. 上海市城区大气VOCs的变化特征及反应活性的初步研究[ D ]. 上海:华东理工大学,2012.
[ 16 ] 谢元博,陈 娟,李 巍. 雾霾重污染期间北京居民对高浓度PM2.5持续暴露的健康风险及其损害价值评估[ J ]. 环境科学,2014,35( 1 ):1 - 8.
[ 17 ] 刘元鹏,仝晓平,牛会明. 汽车空调维修制冷剂作业技术规范的研究[ J ]. 交通标准化,2008,181( 9 ):93 - 96.
[ 18 ] 赵晓辉,郭伯钊,赵校峰. 化学合成制药行业有机废气来源分析与防治技术研究[ J ]. 河南科技,2014,14( 7 ):46 - 47. |
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