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| Electrochemical Oxidation Process of Acid Red B Simulated Wastewater Using Anthraquinone-modified Graphite Felt as Cathode |
| PAN Gui-fang 1, 2, LI Gui-xia 1, 2, ZHAO Jun-na 1, 2, LIU Man 3, GAO Xiang 1, 2, LIU Yan-fang 1, 2,
LI Zai-xing 1, 2 |
| l. School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China; 2. Laboratory of Biological Technology of Containment Prevention of Hebei, Shijiazhuang 050018, China; 3. Hebei Electronic and Information Products Inspection Institute, Shijiazhuang 050071, China |
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Abstract Electrochemical oxidation experiments for acid red B wastewater using Ti/RuO2-IrO2 plate as anode and anthraquinone-modified graphite felt as cathode, were studied respectively. The effects of current, electrolyte concentration, electrolytic time, spacing of plate and the initial pH value on the electrochemical degradation of acid red B were investigated. The results showed that when the concentration of acid red B was 200 mg/L, electric current was 3 A, electrolyte concentration was 0.02mol/L, electrolytic time was 30 min, spacing of plate was 1 cm, and initial pH value was 5.0, the acid red B removals and current efficiency could reach 91.66% and 12.71% respectively. The electrochemical degradation process of acid red B was approximately complied with the first-order kinetics equation ln (c0 / ct) = 0.069 9 t - 0.036 1.
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| [ 1 ] 陈文华,李 刚,许方程,等.染料废水污染现状及处理方法研究进展[J].浙江农业科学,2014(2):264-269.[ 2 ] 蔡 凤,陈芳艳,唐玉斌.酸性红B降解菌的脱色性能[J].净水技术,2013,32(6):45-48.[ 3 ] Nie Yulun, Hu Chun, Qu Jiuhui, et al. Efficient photodegradation of Acid Red B by immobilized ferrocene in the presence of UVA and H2O2[J]. Journal of Hazardous Materials, 2008, 154(304-3 894): 146-152.[ 4 ] Wang Jun, Ma Teng, Zhang Guan, et al. Preparation of novel nanometer TiO2 catalyst doped with up conversion luminescence agent and investigation on degradation of acid red B dye using visible light[J]. Catalysis Communications, 2007( 8 ): 607 - 611.[ 5 ] 华 彬,陆永生,唐春燕,等.超声技术降解酸性红B废水[ J ].环境科学,2000,21( 2 ):88 - 90.[ 6 ] 李文军,胡 翔,康灵玲,等.Fenton试剂催化氧化法处理模拟酸性红B染料废水[J].化工环保,2012,32( 5 ):393- 396.[ 7 ] 李 烨,任海静,栾兆坤.采用双氰胺甲醛缩聚物混凝去除水中酸性红B染料的研究[J].环境工程学报,2008,3(2):362 - 365.[ 8 ] Wu Rongcheng, Qu Jiuhui, He Hong, et al. Removal of azo-dye Acid Red B (ARB) by adsorption and catalytic combustion using magnetic CuFe2O4 powder [J]. Applied Catalysis B: Environmental 2004, 48: 49-56.[ 9 ] Liu Xiaoyu, Zhou Zuoming, Jing Guohua, et al. Catalytic ozonation of Acid Red B in aqueous solution over a Fe-Cu-O catalyst[J]. Separation and Purification Technology, 2013, 115: 129-135.[ 10 ] 岳 琳,王开红,郭建博,等.γ-Al2O3负载磷钨酸催化强化电化学法处理水中酸性大红3R的研究[J].环境科学,2013,34(3):955-961.[ 11 ] 张国芳,肖书虎,肖宏康,等.黄连素制药废水的电化学预处理试验[J].环境科学研究,2011,24(1):79 - 84.[ 12 ] 李 伟,丁 晶,赵庆良,等.电化学氧化法处理垃圾渗滤液中氨氮实验研究[J].哈尔滨商业大学学报(自然科学版),2014,30(1):56-59. [13] 国家环境保护总局.水和废水检测分析方法(第四版)[M].北京: 中国环境科学出版社, 2002.[14] 高俊侠.新型两段式超声强化电化学方法降解染料废水[J].水处理技术,2013,39(9):49-52.[15] 王春荣,李 ,胡建龙,等. 电化学氧化除氨氮过程中羟基自由基及中间产物定量分析[J]. 中国环境科学,2012,32(2):238-241.[16] Murugananthan M, Yoshihara S, Rakuma T, et al. Mineralization of bisphenol A (BPA) by anodic oxidation with boron-doped diamond (BDD) electrode [J]. Journal of Hazardous Materials, 2008, 154(13) 213-220. [17] 周如彬,冉二燕,孙见蕊,等.新型多孔 Ti/BDD 薄膜电极电化学氧化降解低浓度茜素红[J].化工进展,2014,33(1):233-237.[18] Ju Peng, Fan Hai, Guo Doudou, et al. Electrocatalytic degradation of bisphenol A in water on a Ti-based PbO2-ionic liquids (ILs) electrode [J]. Chemical Engineering Journal, 2012 , 179: 99-106.[19] 潘 峰,刘 林,王万峰,等.混凝辅助电化学法处理橙黄 N 染料废水[J].环境工程学报,2013,32(2):3 713-3 718.[20] 葛建团,曲久辉.电化学方法用于酸性红B模拟废水脱色验研究[J].环境污染治理技术与设备,2002,3 (5):12-14.[21] Panizza M, Barbucci A, Delucchi M, et al. Electro-Fenton degradation of anionic surfactants[J]. Separation and Purification Technology, 2013, 118: 394-398.[22] 闫金霞,成庆利. 印染废水治理技术综述[ J ]. 染料与染色.2007,32( 5 ):48 - 51.[23] 胡俊生,任雪冬,马广韬,等. 臭氧高级氧化技术处理酸性红B染料废水[ J ]. 沈阳建筑大学学报(自然科学版),2009,36( 11 ):320-324.[24] 吴志敏,赖经妹,张 丽. 偶氮染料的高铁酸钾脱色及动力 学研究[ J ]. 印染助剂,2010,23(6):24 - 26. [25] 丁 巍,尚 艳. 光助Fenton氧化法降解水中的活性艳蓝KN-R[ J ]. 化工环保,2009,35(5):212 - 215.[26] 李 昊,周 律,李 涛,等. 臭氧氧化法深度处理印染废水生化处理出水[ J ]. 化工环保,2012,32(1):30 - 34. |
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