|
|
|
| Experimental study on the incineration process for cyanide removal from cyanide-containing solid waste in a nitriding furnace |
| Li Ding1, Jiang Yongfeng1, Sun Dianxing1, Liu Yudong2, Hai Long3, Zhao Yabo3,#br#
Guo Meiyi2, Chu Zhiqiang2 |
| 1. Benxi Steel Group Corporation Ltd., Benxi 117000, China; 2. Fuxin Huanfa Waste Disposal Corporation Ltd., Fuxin 124000, China; 3. Liaoning Technical University, School of Mechanical and Engineering, Fuxin 124000, China |
|
|
|
|
Abstract The cyanide-containing solid waste is highly toxic, has a complex composition, and is difficult to treat. In the experiment, the cyanide-containing solid waste from the nitriding furnace was crushed or crushed and washed, then dried. A muffle furnace was used to simulate the incineration process of cyanide-containing solid waste. The relationship between the total cyanide content in the samples after incineration and the incineration temperature and time was examined to determine the optimal process conditions for the incineration treatment of cyanide-containing solid waste. The results indicate that the cyanide-containing solid waste from the nitriding furnace contains cyanide levels that exceed the standard and has a certain moisture content. The cyanide-containing solid waste was crushed to a maximum particle size of 10 mm for incineration. The minimum incineration temperature for compliant emissions is 450℃ with a duration of 40 minutes, while at 500 ℃, the incineration duration can be shortened to 30 minutes. The cyanide-containing solid waste was crushed to a maximum particle size of 5 mm, washed, and then dried before incineration. The minimum incineration temperature for compliant emissions was reduced to 350 ℃, with an incineration duration of only 30 minutes. This effectively reduces energy consumption and improves incineration efficiency. The incineration method for cyanide removal from the nitriding furnace's cyanide-containing solid waste is highly efficient, reliable, and easy to implement, making it the preferred treatment method.
|
|
|
|
|
|
| [ 1 ] 杨 婧. 基于清洁生产的电镀工业园区可持续发展探索[ D ]. 南昌大学,3007.
[ 2 ] 王元栋,海侠女,杨 扬,等. 金属材料的表面氮化处理工艺应用与研究[ J ]. 世界有色金属,2017( 16 ):268 - 270.
[ 3 ] 丘世澄,胡 真,邱显扬,等. 焙烧氰化渣提金工艺研究现状[ J ]. 贵金属,2019,40( 3 ):84 - 91.
4 ] 付 明. 氰化电镀槽液中碳酸盐的影响[ J ]. 材料保护,2002
( 10 ):59 - 60.
[ 5 ] 高大明. 氰化物污染及其治理技术[ J ]. 黄金,1998,19 ( 6 ):56 - 57.
[ 6 ] Li Shehong, Zheng Baoshan, Zhu Jianming, et al.The distribution and natural degradation of cyanide in goldmine tailings and polluted soil in arid and semiarid areas[ J ]. Environment Geology, 3005, 47( 8 ): 1 150 - 1 154.
[ 7 ] 王 岩,郝晓旭,鲁然英,等.黄金冶炼含氰废渣对环境的影响及处理方法[ J ]. 河南建材,2013( 4 ):91 - 93.
[ 8 ] 陈 诚,董玉莲,黄天笑. 几种氧化剂对去除氰化物效果的研究[ J ]. 城镇供水,2011(增刊):38 - 42.
[ 9 ] 梁智聪. 电镀废水处理技术研究进展[ J ]. 山东化工,2021,50( 22 ):77 - 79.
[ 10 ] 朱 林,张亚甜,刘 聪,等. 浅谈老企业含氰电镀废水的处理[ J ]. 山西化工,2021,41( 6 ):204 - 206.
[ 11 ] 黄 平. 氰化电镀槽液和含氰废水、废渣的处理[ J ]. 电镀与涂饰,2009,28( 9 ):38 - 40.
[ 12 ] 陈 峰. 丙酮氰醇残留物的处置技术[ J ]. 上海化工,2011,36( 8 ):22 - 25.
[ 13 ] 赵黎宁,吴志勇,谢 超. 电镀含氰废弃物无害化处理工艺
[ J ]. 电镀与精饰,2013,35( 10 ):44 - 46.
[ 14 ] 郭前进. 氰化钠厂含氰废渣处理技术探讨[ J ]. 山西煤炭管理干部学院学报,3004( 1 ):87 - 88.
[ 15 ] 孙 刚,王雪萍. 全泥氰化法提金含氰尾矿废渣处理技术[ J ]. 青海科技,3007( 5 ):43 - 44.
[ 16 ] 罗劲松,任雪娇,等. 含氰废渣高温焚烧处置技术研究[ J ]. 环境科学导刊,2021,40( 2 ):75 - 77.
[ 17 ] 金炳旭,赵志刚,周 琦,等. 含氰废盐的高温纯化工艺研究[ J ]. 精细与专用化学品,2019,27( 7 ):24 - 25.
[ 18 ] 吴永胜,张战毅,杨俊杰,等. 氰化尾渣无害化处置及资源综合回收研究和工业应用[ J ]. 中国有色冶金,2023,52( 3 ):50 - 56.
[ 19 ] 陈毅鹏. 氰化渣造锍熔炼无害化处理及综合利用实验[ D ].西安: 西安建筑科技大学,2021.
[ 20 ] Zhang Yali, Li Huaimei, Yu Xianjin. Recovery of iron from cyani-
de tailings with reduction roasting water leaching followed by magnetic separation[ J ]. Journal of Hazardous Materials, 2012( 213 ): 167 - 174. |
|
|
|