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| Research on advanced treatment technology of coal chemical wastewater |
| Zhang Qian1,2, Wang Ling1, Guo Xuehua2 |
1. North China University of Science and Technology, Tangshan 063210, China; 2. Coal Chemical R and D Center
of Kailuan Group, Tangshan 063611, China |
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Abstract Wastewater treatment and reuse in chemical industry is one of the key problems in environmental protection field. There are many coal chemical industrial parks in China, and there are many sewage discharge points and complex water quality in the parks, so the task of purification is extremely difficult. The coal chemical wastewater was used as the research object, according to the characteristics of biochemical effluent water quality, the ultrafiltration + nanofiltration as the core of the double membrane advanced treatment technology was developed. The changes of turbidity, CODCr, ammonia nitrogen, total hardness, electrical conductivity, system operating pressure and flux of ultrafiltration membrane of inlet and outlet water were investigated during the process of advanced treatment. The results show that the advanced treatment process can further purify the biochemical effluent, and the CODcr of the effluent is less than 60 mg/L, and the NH3-N is less than 5 mg/L, the Cl- is less than 250 mg/L, the total hardness is less than 20 mg/L, which meet the water quality requirements of supplementary water for industrial circulating cooling water.
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| [ 1 ] 姜 明,李惊鸿,迟 宇. 炼焦化学工业废水的再生利用[ J ]. 燃料与化工,2012,43( 4 ):52 - 54.
[ 2 ] 李 宁. 焦化废水零排放的工程应用[ J ]. 燃料与化工,2018,49( 5 ):53 - 54.
[ 3 ] 马 昕,安东子,寇彦德,等. 焦化废水膜法组合深度处理工艺设计与应用[ J ]. 工业水处理,2017,37( 4 ):102 - 105.
[ 3 ] 陈海斌. 煤化工反渗透浓盐水处理和回用的探讨[ J ]. 神华科技,2012,10( 4 ):86 - 89.
[ 4 ] 张 桐,刘 健,霍卫东,等. 煤化工反渗透浓缩液的“零排放”技术的研究现状[ J ]. 工业水处理,2016,32( 2 ):15 - 19.
[ 5 ] Gerhard Braun, Christine Kleffner. Industrial Water Desalination by Vacuum Multi - Effect Membrane Distillation[ J ]. Chemie Ingenieur Technik, 2019, 91( 10 ): 1 400 - 1 408.
[ 6 ] 徐 富, 关国强, 张彩吉, 等. 6 000 m3/d甲醛产业化工园区污水处理工程案例[ J ]. 广东化工,2019, 46( 10 ):125 - 127.
[ 7 ] 王永华, 赵 科. 超滤-反渗透用于煤化工回用水处理的工程设计[ J ]. 工业水处理,2015, 35( 2 ):97 - 99.
[ 8 ] 邓 倩, 黄满红, 张月洋, 等. 膜蒸馏对4种染料废水的处理特性研究[ J ]. 水处理技术,2019, 45( 3 ):55 - 59.
[ 9 ] Rihua Xiong, Quan Chen, Jie Liu, et al. Experimental study on se-
eded precipitation assisted reverse osmosis for industrial wastewater reuse[ J ]. Journal of Water Process Engineering,2017,( 20 ):78 - 83.
[ 10 ] 李晓芳. 活性炭吸附处理电镀废水的研究[ J ]. 石化技术,2019,( 8 ):154 - 155.
[ 11 ] Ji Ma, Chunting Liu, Kezheng Chen. Removal of Cr(VI) species from water with a newly-designed adsorptive treatment train[ J ]. Separation and Purification Technology, 2020, 234, 116041.
[ 12 ] 李新望, 谷晓娟, 左大海, 等. 陶瓷超滤膜在电厂化学水处理系统改造中的应用[ J ]. 工业水处理,2019,39( 8 ):107 - 110.
[ 13 ] 白春英. 膜分离技术在水处理的应用探微[ J ]. 化工管理,2019,( 26 ):112 - 113.
[ 14 ] 曲风臣. 煤化工废水“零排放”技术要点及存在问题[ J ]. 化学工业,2013,31( 2 ):18 - 24.
[ 15 ] 黄开东,李 强,汪 炎. 煤化工废水“零排放”技术及工程应用现状分析[ J ]. 工业用水与废水,2012,43( 5 ):1 - 6. |
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