双脂肪酸憎水性低共熔溶剂的合成及富集水中铜离子的研究

doi:10.19286/j.cnki.cci.2020.06.034

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Abstract

Hydrophobic deep eutectic solvents (HDES) composed of two fatty acids of different carbon numbers were synthesized. Density and viscosity of the deep eutectic solvent made of two fatty acids which are lauric acid and decanoic aid were measured, and the extraction effect on copper ion in aqueous solution was investigated. The effect of DES amount, copper ion concentrations, volume ratio of extractor to aqueous solution and pH value of the solution on the extraction efficiency of copper ion were investigated respectively. Experimental results indicate that when the molar ratio of lauric acid and decanoic acid is 1∶2, the volume ratio of HDES and copper ion solution is 1∶1, the copper ion concentration is decreased from 10×10-5 to 1.6×10-6, the extraction efficiency goes up to 91%. Meanvohile, HDES mechanical damage can be ignored. The HDES’s thermal stability was characterized by TGA-DSC. A metal complexation mechanism including van der Waals forces for extracting copper ion in aqueous solution was proposed.

Key words： fatty acid hydrophobicity deep eutectic solvent extraction copper ion

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	Articles by authors
	Ma Shangwen1
	Di Mengfei2
	Yang Rongsheng1
	Feng Shubo2
	1

Cite this article:

Ma Shangwen1,Di Mengfei2,Yang Rongsheng1等. Study on extraction of aqueous copper ion using deep eutectic solvent made of two fatty acid components[J]. CCI, 2020, 43(6): 121-128.

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http://www.mtyhg.com.cn/EN/10.19286/j.cnki.cci.2020.06.034 OR http://www.mtyhg.com.cn/EN/Y2020/V43/I6/121

[ 1 ]       陈璐瑶. 液膜法处理含铜废水的试验研究[ J ]. 广州化学，2016，41（ 4 ）：74 - 77.
[ 2 ]       李    想，吴雅琴. 含铜废水治理及资源化利用技术新进展[ J ]. 环境科学与技术，2018，41（ 8 ）：34 - 40.
[ 3 ]       Francisco Maria, van den Bruinhorst Adriaan, Kroon Maaike C. Low-Transition-Temperature Mixtures (LTTMs): A new genera-tion of designer solvents [ J ]. Angew Chem Int Edit, 2013, 52 (11):
               3 074 - 3 085.
[ 4 ]       Smith Emma L, Abbott Andrew P, Ryder, Karl S, Deep eutectic solvents (DESs) and their applications [ J ]. Chem Rev, 2014, 114 ( 21 ): 11 060 - 11 082.
[ 5 ]       Hou Yucui, Yao Congfei, Wu Weize. Deep Eutectic Solvents: Green Solvents for Separation Applications[ J ]. Acta Phys-Chim Sin, 2018, 34 ( 8 ): 873 - 885.
[ 6 ]       岳旭东，袁    冰，朱国强，等. 低共熔溶剂在有机合成和萃取分离中的应用进[ J ]. 化工进展，2018，37（ 7 ）：2 627 - 2 634.
[ 7 ]       胡鹏程，江    伟，钟丽娟. 低共熔溶剂的应用研究进展[ J ].
              现代化工，2018，38（ 10 ）：53 - 57.
[ 8 ]       Ashish Pandey, Rewa Rai, Mahi Pal, et al. How polar are choline chloride-based deep eutectic solvents [ J ]. Chem Phys, 2014, (16): 1 559 - 1 568.
[ 9 ]       侯玉翠，王    震，任树行，等. 低共熔溶剂在混合物分离中的应用[ J ]. 科学通报，2015（ 26 ）：2 490 - 2 499.
[ 10 ]     郭武杰，陈    钢，吴卫泽，等. 低共熔溶剂特性及在分离过
             程中的应用[ J ]. 现代化工，2014（ 4 ）：42 - 45.
[ 11 ]     张欢欢，刘玉婷，李    戎，等. 新型低共熔溶剂的制备、表征
             及物性研究[ J ]. 化学通报，2015，（ 1 ）：73 - 79.
[ 12 ]      Tereshatov E E, Boltoeva M Yu, Folden C M. First evidence of
metal transfer into hydrophobic deep eutectic and low-transition-
temperature mixtures: indium extraction from hydrochloric and oxalic acids [ J ]. Green Chem, 2016, 18: 4 616 - 4 622.
[ 13 ]     DJ van Osch, D Parmentier, CH Dietz. Removal of alkali and transition metal ions from water with hydrophobic deep eutectic solvents [ J ]. Chem Commun, 2016, 52 ( 80 ) : 11 987 - 11 990.
[ 14 ]     Catarina Florindo, Leila Romero, Ignacio Rintoul, et al. From phase change materials to green solvents: hydrophobic low viscous fatty acid-based deep eutectic solvents[ J ]. ACS Sustainable Chem Eng, 2018, 6 ( 3 )：3 888 - 3 895.
[ 15 ]     Pius Dore Ola, Michiaki Matsumoto. Use of deep eutectic solvent as extractant for separation of Fe (III) and Mn (II) from aqueous solution
             [ J ]. J Sep Sci Technol, 2019, 54( 5 ): 759 - 765.
[ 16 ]     Nicolas Schaeffer, Mónia A R Martins, Catarina M S S Neves, et al. Sustainable hydrophobic terpene-based eutectic solvents for the extraction and separation of metals [ J ]. Chem Commun, 2018, 54( 58 ): 8 104 - 8 107.
[ 17 ]     Tim E Phelps, Nakara Bhawawet, Silvia S Jurisson, et al. Efficient and Selective Extraction of 99mTcO4- from Aqueous Media Using Hydrophobic Deep Eutectic Solvents [ J ]. ACS Sustainable Chem
              Eng, 2018, 6 ( 11 ): 13 656 - 13 661.
[ 18 ]      Tang Weiyang, Dai Yunliang, Kyung Ho Row. Evaluation of fatty acid/alcohol-based hydrophobic deep eutectic solvents as media for extracting antibiotics from environmental water [ J ]. Anal Bioanal Chem, 2018, 410 ( 28 ): 7 325 - 7 336.
[ 19 ]     冯树波，马尚文，宋弥新，等。憎水性低共熔溶剂的合成及在萃取分离领域中的应用研究进展[ J ].化学研究与应用，2020，32（ 2 ）：177 - 186.
[ 20 ]     熊大珍，张    倩，樊    静，等. 疏水性低共熔溶剂及其在含水体系萃取分离中的应用[ J ]. 中国科学：化学，2019，49（ 7 ）：933 - 939.
[ 21 ]     Zubeir Lawien F, van Osch Dannie J G P, Rocha Marisa A A, et al. Carbon Dioxide Solubilities in Decanoic Acid-Based Hydrophobic Deep Eutectic Solvents [ J ]. J Chem Eng Data, 2018, 63 ( 4 ): 913 - 919.
[ 22 ]     Makos Patrycja, Przyjazny Andrzej, Boczkaj Grzegorz. Hydrophobic deep eutectic solvents as "green" extraction media for polycyclic aromatic hydrocarbons in aqueous samples [ J ]. J Chromatogr A, 2018, 1 570: 28 - 37.
[ 23 ]     Giorgia Sed, Agnese Cicci, Philip G Jessop et al. A novel switchable
-hydrophilicity, natural deep eutectic solvent (NaDES) -based system for bio-safe biorefinery[ J ]. RSC Adv, 2018, 8: 37 092 - 37 097.
[ 24 ]     Zeliha Erbas, Mustafa Soylak, Erkan Yilmaz, et al. Deep eutectic solvent based liquid phase microextraction of nickel at trace level as its diethyldithiocarbamate chelate from environmental samples，Microchemical Journal, 2019, 145: 745 - 750.
[ 25 ]     S Ruggeri, F Poletti, C Zanardi et al. Chemical and electrochemical properties of a hydrophobic deep eutectic solvent [ J ]. Electrochi-
mica Acta, 2019, 295: 124 - 129.
[ 26 ]     Tiemei Li, Yuefei Song, Jingjie Xu, et al. A hydrophobic deep eutectic solvent mediated sol-gel coating of solid phase microextraction fiber for determination of toluene, ethylbenzene and o-xylene in water coupled with GC-FID, Talanta, 2019, 195: 298 - 305.
[ 27 ]     Ehsan Reyhanitash, Thomas Brouwer, Sascha R A Kersten A G J van der Ham Boelo Schuur, Liquid-liquid extraction-based process concepts for recovery of carboxylic acids from aqueous streams evaluated for dilute streams[ J ]. Chem Eng Res Des, 2018, 137: 510 - 533.