离子液体催化芳烃硝化反应研究进展

doi:10.19286/j.cnki.cci.2020.12.033

Abstract
Figure/Table
References (28)
Related Citation (15)

Download: PDF (0 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract

The nitrification products of aromatic compounds are widely used in industry. The traditional nitrification reaction process was using concentrated sulfuric acid as catalyst. Although the operation condition is mature, it has strong corrosivity and is difficult to treat. In recent years, as the study of green catalysts, the green catalytic nitrification system which could replace the traditional nitrification system of mixed acid has attracted wide research interests. So, using new green functional ionic liquids as environment-friendly nitrification catalyst for realizing green and clean nitrification reaction become a research hotspot. The research progress of ionic liquids used in aromatics nitration reaction was reviewed, and the ionic liquids showed an ideal green catalytic prospect.

Key words： ionic liquid aromatic compounds catalyze nitration

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Liu Yueming1
	Liu Chen1
	2
	Liu Ran1
	Zhang Ke1
	Zhang Juan1
	Zhao Dishun1

Cite this article:

Liu Yueming1,Liu Chen1,2等. Research progress on nitrification of aromatic compounds catalyzed by ionic liquids[J]. CCI, 2020, 43(12): 111-117.

URL:

http://www.mtyhg.com.cn/EN/10.19286/j.cnki.cci.2020.12.033 OR http://www.mtyhg.com.cn/EN/Y2020/V43/I12/111

[ 1 ]       Wu H, Yan H Y, Quan Y, et al. Recent progress and perspectives in biotrickling filters for VOCs and odorous gases treatment[ J ]. Journal of Environmental Management, 2018 (222): 409 - 419.
[ 2 ]       Liu Y H, Wang H L, Jing S G, et al. Strong regional transport of volatile organic compounds (VOCs) during wintertime in Shanghai megacity of China[ J ]. Atmospheric Environment, 2020 (210): 332 - 341.
[ 3 ]       Zhou K, Ma W W, Zeng Z, et al. Experimental and DFT study on the adsorption of VOCs on activated carbon/metal oxides composites[ J ]. Chemical Engineering Journal, 2019 (372): 1 122 - 1 133.
[ 4 ]       Zhu S P, Kinnon M M, Shaffer B P., et al. An uncertainty for clean air: Air quality modeling implications of underestimating VOC emissions in urban inventories[ J ]. Atmospheric Environment, (211): 256 - 267.
[ 5 ]       Liang Z S, Wang J J, Zhang Y N, et al. Removal of volatile organic compounds (VOCs) emitted from a textile dyeing wastewater treatment plant and the attenuation of respiratory health risks using a pilot-scale biofilter[ J ]. Cleaner Production, 2020 (253):19 - 120.
[ 6 ]       岑超平，陈定盛，蓝如辉，等. 吸收法脱除甲苯废气的实验研究[ J ]. 环境工程，2007，25（ 5 ）：40 - 43.
[ 7 ]       刘    攀. 芳烃绿色硝化催化剂的研究进展[ J ]. 化学工程师，2014，28（ 4 ）：36 - 41.
[ 8 ]       Deng R J, You, K Y, Ni W J, et al. Low-temperature and highly efficient liquid-phase catalytic nitration of chlorobenzene with NO2: Remarkably improving the para-selectivity in O2-Ac2O-Hβ composite system[ J ].. Applied Catalysis A: General, 2020 (594): 117 - 468.
[ 9 ]       Peng X H, Fukui N, Mizuta M, et al. Nitration of moderately deac-
tivated arenes with nitrogen dioxide and molecular oxygen under neutral conditions. Zeolite-induced enhancement of regioselectivity and reversal of isomer ratios[ J ]. Organic & Biomolecular Chemis-
try, 2003, 1 ( 13 ): 2 326 - 2 335.
[ 10 ]     Bemasconi S, Plmgruber G D, Prins R. Influence of the properties of Zeolite BEA on its performance in the nitration of toluene and nitrotoluene [ J ]. Catalysis, 2004, 224( 2 ): 297 - 303.
[ 11 ]     Lancaster N L, Llopis-Mestre V. Aromatic nitrations in ionic liquids: the importance of cation choice[ J ]. Chemical Communications, 2003 (22): 2 812 - 2 813.
[ 12 ]     Earle M J, Katdare S P, Seddon K. R. Paradigm confirmed: the first use of ionic liquids to dramatically influence the outcome of chemical reactions[ J ]. Organic Letters, 2004, 6( 5 ): 707 - 710.
[ 13 ]     Smith K, Liu S F, Elhiti G A. Regioselective mononitration of simple aromatic compounds under mild conditions in ionic liquids[ J ]. Industrial & Engineering Chemistry Research, 2005, 44( 23 ): 8 611 - 8 615.
[ 14 ]     Laali K K. Tailoring Adsorption-Desorption Properties of Hydroa-
mination Catalysts with Ionic Liquids[ C ]. [ACS Symposium Series] Ionic Liquids in Organic Synthesis, 2007, 950(Ⅱ): 267 - 280.
[ 15 ]     施群荣. 离子液体催化甲苯绿色硝化的应用研究[ D ]. 南京：南京理工大学，2007.
[ 16 ]     Cheng G B, Duan X L, Qi X F, et al. Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquids[ J ]. Catalysis Communications, 2008, 2( 10 ): 201 - 204.
[ 17 ]     张    丽，郭    艳，王素莉，等. Bronsted酸离子液体的制备及其在氯苯选择性硝化中的应用研究[ J ]. 化工中间体，2009（ 3 ）：19 - 24.
[ 18 ]     齐秀芳，程广斌，吕春绪. 酸性离子液体存在下甲苯的硝酸硝化（II）[ J ]. 含能材料. 2009，17（ 6 ）：717 - 721.
[ 19 ]     李    霞. Bronsted酸性离子液体存在下乌洛托品和甲苯的硝化反应研究[ D ]. 南京：南京理工大学，2009.
[ 20 ]     钱德胜，程广斌，吕春绪. 稀土金属在离子液体中催化甲苯的硝化反应[ J ]. 应用化学，2009，26（ 7 ）：757 - 761.
[ 21 ]     Yang H W, Qi X F, Wen L, et al. Regioselective mononitration of aromatic compounds using keggin heteropolyacid anion based br?nsted acidic ionic salts[ J ]. Industrial & Engineering Chemistry Research, 2011, 50 ( 19 ): 11 440 - 11 444.
[ 22 ]     姜晓健. 离子液体催化硝化乙苯研究[ D ]. 南京：南京大学，2012.
[ 23 ]     Zolfigo M A, Khazaei A, Moosavi-Zare A, et al. Design of ionic liquid 3-methyl-1-sulfonic acid imidazolium nitrate as reagent for the nitration of aromatic compounds by in situgeneration of NO2 in acidic media [ J ]. Organic Chemistry, 2012, 77( 7 ): 3 640 - 3 645.
[ 24 ]     刘丽荣，职慧珍，罗    军，等. 新型酸性离子液体催化下甲苯的选择性硝化[ J ]. 含能材料，2008，16（ 4 ）：398 - 400.
[ 25 ]     Wang S J, Jiang S J, Nie J. Lanthanide bis[(trifluoromethyl)sul-fonyl] imides as reusable catalysts for mononitration of substituted benzenes in lonic liquids [ J ]. Advanced Synthesis & Catalysis, 2009, 351(11-12): 1 939 - 1 945.
[ 26 ]     Qiao K, Hagiwara H., Yokoyama C. Acidic ionic liquid modified silicagel as novel solid catalysts for esterification and nitration reactions[ J ]. Journal of Molecular Catalysis A: Chemical, 2006, 246(1-2): 65 - 69.
[ 27 ]     凌七龙. 聚苯乙烯负载离子液体的制备及催化甲苯硝化的应用研究[ D ]. 南京：南京理工大学，2012.
[ 28 ]     李丽霞. 新型交联高分子载体材料的设计、制备及在催化反应中的应用[ D ]. 南京：南京理工大学，2013.