γ-Al2O3催化臭氧氧化水中双酚A动力学研究

doi:10.19286/j.cnki.cci.2019.12.029

Abstract
Figure/Table
References (23)
Related Citation (1)

Download: PDF (0 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract

The kinetic of γ-Al2O3 catalytic ozonation of bisphenol in water was studied using competitive kinetic method with phenol as a competitor. At room temperature and atmospheric pressure, the effects of catalyst dosage, ozone dosage and pH on the reaction rate constant kBPA were investigated. Results showed that the process of the ozonation of BPA by γ-Al2O3 accords with the first-order reaction kinetics model. The kBPA has a positive correlation with catalyst dosage(2-10 mg / L), and its range is 1.98×106 — 2.18×106 M-1·s-1. With the increase of the ozone dosage (3.97-8.5 mg/min), kBPA has a maximum value which is 2.33×106 M-1·s-1 when the ozone dosage is 6.52 mg / min. The initial pH value has a greater impact on kBPA, and with the increase of pH (3.0-11.0), kBPA increases exponentially from 1.43×103 to 1.77 × 109 M-1 ·s-1.

Key words： γ- Al2O3 catalytic ozonation bisphenol A competitive kinetic reaction rate constant

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Wu Zhijie1
	Chen Jiaxin1
	Tong Jiapeng1
	Yu Fei1
	Liu Mengna1
	Wang Shumeng1
	Liu Yanfang*1
	2

Cite this article:

Wu Zhijie1,Chen Jiaxin1,Tong Jiapeng1等. Study on kinetic of γ-Al2O3 catalytic ozonation of bisphenol in water[J]. CCI, 2019, 42(12): 110-114,117.

URL:

http://www.mtyhg.com.cn/EN/10.19286/j.cnki.cci.2019.12.029 OR http://www.mtyhg.com.cn/EN/Y2019/V42/I12/110

[ 1 ]       黄晓明，余长亮，熊光胜. 纳米TiO2光催化氧化降解双酚A研究[ J ]. 江西化工，2010（ 1 ）：90 - 94.
[ 2 ]       Huang Y Q, Wong C K C, Zheng J S, et al. Bisphenol A ( BPA ) in China: A review of sources, environmental levels, and potential human health impacts [ J ]. Environment International, 2012; 42:
              91 - 99.
[ 3 ]       Tiwari D, Kamble J, Chilgunde S, et al. Clastogenic and mutagenic effects of bisphenol A: An endocrine disruptor[ J ]. Mutation Research/Genetic Toxicology and Environmental Mutagenesis, 2012; 743( 1-2 ): 83 - 90.
[ 4 ]       Yi B, Kasai H, Lee H, et al. Inhibition by wheat sprout (Triticuma-
estivum) juice of bisphenol A - induced oxidative stress in young women[ J ]. Mutation Research/Genetic Toxicology and Environ-
mental Mutagenesis, 2011, 24 ( 1 - 2 ): 64 - 68.
[ 5 ]       Salgueiro-González N, Concha-Grana E, Turnes-Carou I, et al. Determination of alkylphenols and bisphenolA in seawater samples by dispersive liquid - liquid microextraction and liquid chromatography tandem mass spectrometry for compliance with environmental quality standards[ J ]. Journal of Chromatography
              A, 2012 ( 1 223 ) 1 - 8.
[ 6 ]       张玉富. 苏州市主要水体、饮用水及餐饮用具双酚A污染状况调查及其去除方法研究[ D ]. 苏州大学，2012.
[ 7 ]       克    选. 加速溶剂萃取气相色谱-质谱法检测土壤中双酚A[ J ]. 中国测试，2016（ 3 ）：45 - 47.
[ 8 ]       张海峰，胡建英，常    红，等. SPE-LC-MS法检测杭州地区饮用水水源及自来水中的双酚A[ J ]. 环境化学，2004
           （ 5 ）：584 - 586.
[ 9 ]       金士威，徐    盈，惠    阳，等. 污水中8种雌激素化合物的
             定量测定[ J ]. 中国给水排水，2005（ 12 ）：94 - 97.
[ 10 ]     尹丽丽. 含双酚A的废水处理[ J ]. 辽宁化工，2014（ 3 ）：282 - 284.
[ 11 ]     杨晓春，戴荣海，刘振鸿，等. 水中典型内分泌干扰物双酚A的去除技术研究进展[ J ]. 环境工程，2013（ 1 ）：135 - 138.
[ 12 ]     Zhao J, Zhu C, Lu J, et al. Electro-catalytic degradation of bisph-
enol A with modified Co3O4/β - PbO2/Ti electrode[ J ]. Electrochi-
              micaActa, 2014, 118: 169 - 175.

[ 13 ]     张笑真. 高级氧化法去除饮用水中双酚A的技术浅析[ J ]. 净水技术，2016（ 1 ）：25 - 29.
[ 14 ]     宋丽红，李    娟，宛中华，等. 类芬顿法降解环境内分泌干扰物双酚A的研究进展[ J ]. 重庆理工大学学报（自然科学），2014（ 8 ）：64 - 70.
[ 15 ]     Li S, Ma Z, Wang L, et al. Influence of MnO2 on the photocatalytic activity of P-25 TiO2 in the degradation of methyl orange[ J ]. Science in China Series B: Chemistry, 2008, 51( 2 ): 179 - 185.
[ 16 ]     Liu Y, Zhang M, Zhang J, et al. A simple method of fabricating large-area α-MnO2 nanowires and nanorods[ J ]. Journal of Solid State Chemistry, 2006, 179( 6 ): 1 757 - 1 761.
[ 17 ]     王    昶，梁晓霞，豆宝娟，等. γ-Al2O3催化臭氧氧化降解偶氮染料橙黄G的研究[ J ]. 环境工程，2014，32（ 4 ）：41 - 45.
[ 18 ]     魏    健，孔明昊，宋永会. γ-Al2O3/O3多相催化氧化深度处理制药尾水[ R ]. 2016中国环境科学学会学术年会. 北京：中国环境科学学会，2016：2 200 - 2 205.
[ 19 ]     莫立焕，谈金强，王聪聪，等. γ-Al2O3催化臭氧深度处理蔗渣制浆废水[ J ]. 华南理工大学学报：自然科学版，2017，（ 2 ）：144 - 152.
[ 20 ]     臧兴杰. 臭氧及同相催化臭氧化降解有机物的动力学研究[ D ]. 浙江工业大学，2009.
[ 21 ]     任霁晴，贾大兵，壮亚峰. 紫外分光光度法测定塑料制品中双酚A[ J ]. 吉林化工学院学报，2007（ 4 ）：40 - 42.
[ 22 ]     张    轶，黄若男，王晓敏，等. TiO2光催化联合技术降解苯酚机制及动力学[ J ]. 环境科学，2013（ 2 ）：596 - 603.
[ 23 ]     Sánchez - Acevedo Z C, Riu J, Rius F X. Fastpicomolar selective detection of bisphenol A in water using a carbon nanotube field effect transistor functionalized with estrogen receptor-α. Biosensors and Bioelectronics, 2009, 24( 9 ): 2 842 - 2 846.