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| Research on Degradation of Congo Red by Sodium Persulfate Activated with Resin Supported Nano Zero-valent Iron |
| ZHENG Xiao-hua1, WANG Li-na2, REN Li2 |
| 1. Qinggong College, Hebei United University, Tangshan 063000,China; 2. Qian'an College, Hebei United University, Tangshan 064400,China |
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Abstract Oxidative degradation of congo red (CR) in aqueous solution by resin of zero valent iron nanoparticles (NZVI, nanoscale zero-valentiron)and activated sodium peroxydisulfate (PDS) was investigated. The degradation process was based on generation of sulfate radicalsas powerful oxidizing species. The effects of temperature, pH value, the dosages of NZVI-resin, the concentration of sodium persulfate on congo red were examined in batch experiments. In addition, its degradation kinetics was discussed. The results showed that under the condition of pH = 3, Fe0 dosage 0.067 g·L-1, Na2S2O8 dosage 0.67 g·L-1, the degradation efficiency of a initial CR concentration 20 mg·L-1could reach 84.59%,and the degradation of congo red followed the first order kinetics.
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| [ 1 ] Solpan D, Guven O. Decoloration and degradation of some textile dyes by gamma irradiation[ J ]. Radiation Physics and Chemistry, 2002, 65(4 ):549 - 558.[ 2 ] Zhou Qi xing. Chemical pollution and transport of organic dyes in water- soil crop systems of the Chinese coast [ J ]. Bulletin of Environmental Contamination and Tox icology,2001,66( 6 ) :784 - 793.[ 3 ] 何 强,龙腾锐.印染废水治理技术评价[ J ]. 给水排水, 1995,(5 ):47 - 50.[ 4 ] 李家珍. 染料工业废水处理刍议[ J ]. 环境工程,1988,6(2 ):17 - 22.[ 5 ] 李 庄,曾光明,高兴斋.偶氮染料废水处理研究现状及其发展方向 [ J ].湖南化工,2000,30(6 ):12 - 15.[ 6 ] 郭延辉.纳米零价铁对染料废水的脱色性能研究[ D ].河南师范大学,2009.[ 7 ] 杨世迎, 陈友媛,胥慧真,等. 过硫酸盐活化高级氧化新技术[ J ].化学进展,2008, 20(9 ) :1 433 - 1 438.[ 8 ] House D A.Kinetics and mechanism of oxidations by peroxydisulfate[ J ].Chem Rev,1962,62(3 ) :185 - 203.[ 9 ] 杨世迎,杨 鑫,王 萍,等. 过硫酸盐高级氧化技术的活化方法研究进展[ J ]. 现代化工,2009,29(4 ):23 - 25.[ 10 ] 闫金霞,董韶峰,永强等.零价铁法处理染料废水脱色效果研究[ J ]. 染料与染色,2007,44 (4 ):45 - 46.[ 11 ] 贾汉忠,宋存义,李 晖.纳米零价铁处理地下水污染技术研究进展[ J ]. 化工进展,2009,28(11 ):2 028 - 2 034.[ 12 ] Li F, Vipulanandan C, Mohanty K K. Microemulsion and solution approaches to nanoparticle iron production for degradation of tri-chloroethylene[ J ]. Colloid Surface A, 2003, 223:103 - l12.[ 13 ] I Hussain, Y Q Zhang,S B Huang, et al.Degradation of p-chloroaniline by persulfate activated with zero-valentiron [ J ].Chemical Engineering Journal, 2012, 203:269 - 276. |
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